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lawyer [7]
2 years ago
9

What are the period and group trends in electronegativities

Chemistry
1 answer:
Leviafan [203]2 years ago
8 0

Electronegativity of an element decreases as we move down a group on the periodic table and electronegativity increases while moving from left to right across a period on the periodic table.

Explanation:

  • The electronegativity increases as we move from left to right across a period because from left to right across a period, the nuclear charge is increasing Hence the attraction for the valence electrons also increases.
  • As we move down a group, the atoms of each element have an increasing number of energy levels. The distance between the nucleus and valence electron shell increases and reduces the attraction for valence electrons. Hence electronegativity decreases as we move from top to bottom down a group.
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true

Explanation:

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Using any data you can find in the ALEKS Data resource, calculate the equilibrium constant K at 30.0 °C for the following reacti
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Answer : The value of K for this reaction is, 2.6\times 10^{15}

Explanation :

The given chemical reaction is:

CH_3OH(g)+CO(g)\rightarrow HCH_3CO_2(g)

Now we have to calculate value of (\Delta G^o).

\Delta G^o=G_f_{product}-G_f_{reactant}

\Delta G^o=[n_{HCH_3CO_2(g)}\times \Delta G^0_{(HCH_3CO_2(g))}]-[n_{CH_3OH(g)}\times \Delta G^0_{(CH_3OH(g))}+n_{CO(g)}\times \Delta G^0_{(CO(g))}]

where,

\Delta G^o = Gibbs free energy of reaction = ?

n = number of moles

\Delta G^0_{(HCH_3CO_2(g))} = -389.8 kJ/mol

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\Delta G^0_{(CO(g))} = -137.2 kJ/mol

Now put all the given values in this expression, we get:

\Delta G^o=[1mole\times (-389.8kJ/mol)]-[1mole\times (-163.2kJ/mol)+1mole\times (-137.2kJ/mol)]

\Delta G^o=-89.4kJ/mol

The relation between the equilibrium constant and standard Gibbs, free energy is:

\Delta G^o=-RT\times \ln K

where,

\Delta G^o = standard Gibbs, free energy  = -89.4 kJ/mol = -89400 J/mol

R = gas constant  = 8.314 J/L.atm

T = temperature  = 30.0^oC=273+30.0=303K

K = equilibrium constant = ?

Now put all the given values in this expression, we get:

-89400J/mol=-(8.314J/L.atm)\times (303K)\times \ln K

K=2.6\times 10^{15}

Thus, the value of K for this reaction is, 2.6\times 10^{15}

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B.
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