20points
2 answers:
You might be interested in
Answer:
1) HCl contains the Cl^- which is a good nucleophile
2) 2-methyl-2- heptanol > 2-heptanol > 1-heptanol
3) see image attached
Explanation:
If the dehydration of alcohols is carried out using HCl, the chloride ion which is a good nucleophile will attack the substrate to yield an undesirable product.
The dehydration of alcohols is an E1 reaction. Recall that the ease of E1 reaction increases in the order 3°> 2°> 1°. Hence, 2-methyl-2- heptanol forms a tertiary carbocation intermediate during dehydration and has the greatest ease of dehydration.
The three products formed during the dehydration of 3,3-dimethyl-2-butanol are shown in the image attached. Two out of the three are formed by rearrangement reactions.
