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seraphim [82]
2 years ago
5

A 25.0 ml sample of an unknown monoprotic acid was titrated with 0.12 m naoh. the student added 31.6 ml of naoh and went past th

e equivalence point. which procedure could be performed next to more accurately determine the concentration of the unknown acid?
Chemistry
1 answer:
Inessa05 [86]2 years ago
7 0
The procedure, which can be used to determine more accurately the concentration of the unknown acid is TO BACK-TITRATE WITH ADDITIONAL HYDROCHLORIC ACID TO NEUTRALIZE THE ADDITIONAL SODIUM HYDROXIDE THAT WAS ADDED.
Monoprotic acids are acids that can donate only one proton per each molecule and they have only one equivalence point. Examples of monoprotic acids are HCI, HNO3 and CH3COOH.
The back titration method is typically used when one needs to determine the concentration of an analyte provided there is a known molar concentration of excess reactants. 
From the information given in the question above, we are told that excess NaOH was added. To correct this mistake, the right thing to do is to use additional HCl to carry out back titration, taking note of the quantity of acid that will be needed to neutralize the excess NaOH.
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What is/are the principal product(s) formed when excess methylmagnesium iodide reacts with p-hydroxyacetophenone?
Montano1993 [528]

The end product will depend upon

a) the amount of the reagent taken

b) the final treatment of the reaction

If we have just taken methylmagnesium iodide and p-hydroxyacetophenone, then we will get methane and hydroxyl group substituted with MgI in place of hydrogen

Figure 1

However if we have taken excess of methylmagnesium iodide which is Grignard's reagent followed by hydrolysis we will get different product

Figure 2

5 0
3 years ago
When working with hazardous substances in the laboratory your partner splashes a small amount of Sodium Hydroxide onto their clo
alexira [117]

Answer:

a) After helping our partner, we should immediately report the incident to the lab manager or any person in charge of the emergencies occurring in the lab.

b) We should have a copy of the Material Safety Data Sheet to give to the responders. This is because the responder can identify what materials were being used by the person ans what other security measures need to be taken.

5 0
3 years ago
How many atoms are in a sample of 1.83 moles of potassium (K) atoms? Please explain the conversions to me. Thank you!
IRINA_888 [86]
1 mole K ------------- 6.02x10²³ atoms
1.83 moles K ------ ?? atoms

1.83 x (6.02x10²³) / 1 =

1.101x10²⁴ atoms of K

hope this helps!
6 0
3 years ago
A 1.00 g sample of a metal X (that is known to form X ions in solution) was added to 127.9 mL of 0.5000 M sulfuric acid. After a
Semenov [28]

<u>Answer:</u> The metal having molar mass equal to 26.95 g/mol is Aluminium

<u>Explanation:</u>

  • To calculate the number of moles for given molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}     .....(1)

Molarity of NaOH solution = 0.5000 M

Volume of solution = 0.03340 L

Putting values in equation 1, we get:

0.5000M=\frac{\text{Moles of NaOH}}{0.03340L}\\\\\text{Moles of NaOH}=(0.5000mol/L\times 0.03340L)=0.01670mol

  • The chemical equation for the reaction of NaOH and sulfuric acid follows:

2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O

By Stoichiometry of the reaction:

2 moles of NaOH reacts with 1 mole of sulfuric acid

So, 0.01670 moles of NaOH will react with = \frac{1}{2}\times 0.01670=0.00835mol of sulfuric acid

Excess moles of sulfuric acid = 0.00835 moles

  • Calculating the moles of sulfuric acid by using equation 1, we get:

Molarity of sulfuric acid solution = 0.5000 M

Volume of solution = 127.9 mL = 0.1279 L    (Conversion factor:  1 L = 1000 mL)

Putting values in equation 1, we get:

0.5000M=\frac{\text{Moles of }H_2SO_4}{0.1279L}\\\\\text{Moles of }H_2SO_4=(0.5000mol/L\times 0.1279L)=0.06395mol

Number of moles of sulfuric acid reacted = 0.06395 - 0.00835 = 0.0556 moles

  • The chemical equation for the reaction of metal (forming M^{3+} ion) and sulfuric acid follows:

2X+3H_2SO_4\rightarrow X_2(SO_4)_3+3H_2

By Stoichiometry of the reaction:

3 moles of sulfuric acid reacts with 2 moles of metal

So, 0.0556 moles of sulfuric acid will react with = \frac{2}{3}\times 0.0556=0.0371mol of metal

  • To calculate the molar mass of metal for given number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

Mass of metal = 1.00 g

Moles of metal = 0.0371 moles

Putting values in above equation, we get:

0.0371mol=\frac{1.00g}{\text{Molar mass of metal}}\\\\\text{Molar mass of metal}=\frac{1.00g}{0.0371mol}=26.95g/mol

Hence, the metal having molar mass equal to 26.95 g/mol is Aluminium

6 0
3 years ago
2.00 L of 0.800 M NaNO3 must be prepared from a solution known to be 2.50 M in concentration.How many mL are required? Plus don'
Morgarella [4.7K]

Answer:

1.36 × 10³ mL of water.

Explanation:

We can utilize the dilution equation. Recall that:

\displaystyle M_1V_1= M_2V_2

Where <em>M</em> represents molarity and <em>V</em> represents volume.

Let the initial concentration and unknown volume be <em>M</em>₁ and <em>V</em>₁, respectively. Let the final concentration and required volume be <em>M</em>₂ and <em>V</em>₂, respectively. Solve for <em>V</em>₁:

\displaystyle \begin{aligned} (2.50\text{ M})V_1 &= (0.800\text{ M})(2.00\text{ L}) \\ \\ V_1 & = 0.640\text{ L} \end{aligned}

Therefore, we can begin with 0.640 L of the 2.50 M solution and add enough distilled water to dilute the solution to 2.00 L. The required amount of water is thus:
\displaystyle 2.00\text{ L} - 0.640\text{ L} = 1.36\text{ L}

Convert this value to mL:
\displaystyle 1.36\text{ L} \cdot \frac{1000\text{ mL}}{1\text{ L}} = 1.36\times 10^3\text{ mL}

Therefore, about 1.36 × 10³ mL of water need to be added to the 2.50 M solution.

8 0
2 years ago
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