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My name is Ann [436]
3 years ago
7

The hydrolysis of ethyl acetate (CH3COOC2H5) by sodium hydroxide yields ethanol (C2H5OH) and sodium acetate (NaO2CCH3) by the re

action shown, which follows second order kinetics. In an experiment 500 mL of 0.1 M ethylacetate in water is mixed with 500 mL of 0.1 M NaOH in water. After 20 minutes the concentration of sodium acetate is measured and is 0.0435M. Determine the rate constant for the reaction.
CH3COOC2H5 + NaOH C2H5OH + NaO2CCH3

A) 0.002 L mol-1s-1 B) 0.11 s-1 C) 0.11 L mol-1 s-1 D) 0.3 L mol-1 s-1 E) 0.5 L mol-1 s-1
Chemistry
1 answer:
devlian [24]3 years ago
6 0

Answer:

0.02

Explanation:

work using rate law

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A. Clearly draw the Lewis structure for the PBr4- ion. Show your math where
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Answer:

   Br

    |

Br-P-Br

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Explanation:

To calculate the valance electrons, look at the periodic table to find the valance electrons for each atom and add them together. P is in column 5A, so it has 5, Br is in column 7A, so it has 7 (multiply by 4 since there are 4 Br atoms to give 28) and there is a 1- charge, so add one more electron. 5+28+1=34, so there are 34 electrons to place. P would be the central atom, so place it in the middle. Place each Br around the P (as shown above) with a a single line connecting it. Each line represents 2 electrons, so 8 total have been place, leaving 26 remaining. Place 6 electrons around each Br (2 on each of the unbonded sides), which leaves 2 electrons remaining. The remaining pair of unbound electrons will be attached to the P between any two Br atoms. Phosphorus doesn't have to follow the octet rule, so it actually ends up with 10 valance electrons.

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Which elements have the quantum numbers (4,3,-2,+1/2) and (5,2,-1,-1/2)
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The elements are samarium (Sm) and silver (Ag).  

<em>Quantum numbers (4,3,-2,+½)  </em>

<em>n</em> = 4: Principal quantum number = 4.  

<em>l</em> = 3: Element has 4f electrons  

It is <em>conventional</em> to list quantum numbers in decreasing order.  

<em>Hund’s rule </em>states that all the orbitals must be half-filled with electrons having the same spin before any can receive a second electron.  

We get the following table:  

<u>Element </u><em><u>n</u></em><u> </u><em><u>l</u></em><u>   </u><em><u>m</u></em><u>ₗ </u><em><u>m</u></em><u>ₛ</u>  

    La      4 3   3 +½  

    Ce     4 3   2 +½  

    Pr      4 3   1  +½  

    Nd    4 3   0 +½  

    Pm   4 3  -1   +½  

    Sm   4 3 -2 +½  

The element is samarium, Sm.  

<em>Quantum numbers (5,2,-1,-½)  </em>

<em>n</em> = 5: Principal quantum number = 5.  

<em>l</em> = 2: Element has <em>5d</em> electrons  

We get the following table:  

<u>Element </u><em><u>n</u></em><u>  </u><em><u>l m</u></em><u>ₗ mₛ</u><em><u>  </u></em>

<em>  </em>   Y       5<em> </em>2  2 +½  

    Zr      5 2  1 +½  

    Nb    5 2  0 +½  

    Mo   5 2  -1 +½  

    Tc    5 2  -2 +½  

    Ru   5 2   2  -½  

    Rh   5 2   1   -½  

    Pd   5 2   0  -½  

    Ag   5 2  -1  -½  

The element is silver, Ag.

<em>Note</em>: These assignments assume that there are <em>no exceptions</em> in the Periodic Table.

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