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Leviafan [203]
3 years ago
7

A 8.00 L tank at 26.9 C is filled with 5.53 g of dinitrogen difluoride gas and 17.3 g of sulfur hexafluoride gas. You can assume

both gases behave as ideal gases under these conditions. Calculate the mole fraction and partial pressure of each gas, and the total pressure in the tank
Chemistry
1 answer:
pshichka [43]3 years ago
6 0

Answer:

mole fraction of N_2 O = 0.330

mole of fraction SF_4 = 0.669

PRESSURE OF N_2 O = 39127.053 Pa

pressure of SF_4 = 792126.36

Total pressure   = 118253.413 Pa

Explanation:

Given data:

volume of tank 8 L

Weight of dinitrogen difluoride gas 5.53 g

weight of sulphur hexafluoride gas 17.3 g

Amount of N_2 O = \frac{5.53}{14*2 + 16} = 0.1256 mol

amount of SF_4 = \frac{17.3}{32.1 + 19*4} = 0.254 mol

mole fraction of N_2 O = \frac{0.1256}{0.1256 + 0.254} = 0.330

mole of fractionSF_4 = \frac{0.254}{0.1256 + 0.254} = 0.669

PV = nRT

P of N_2 O = \frac{0.1256 *8.31 (273 + 26.9}{0.008} = 39127.053 Pa

mole of SF_4=\frac{0.254 *8.31*(273+26.9)}{.008} = 79126.36 Pa

Total pressure  = 39127.053 + 79126.36 = 118253.413 Pa

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When 80 g of sodium hydroxide, naoh, are dissolved in enough water to make 500 ml of solution, the molarity of the solution is?
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5. Write a net ionic equation that occurs in a Na2HPO4/NaH2PO4 buffer solution when: A) a small amount of HCl is added (2 points
labwork [276]

Answer: (A) H_{3}O^{+}(aq) + HPO^{2-}_{4}(aq) \rightarrow H_{2}PO^{2-}_{4}(aq) + H_{2}O(l)

(B) H_{2}PO^{-}_{4}(aq) + OH^{-}(aq) \rightarrow HPO^{2-}_{4}(aq) + H_{2}O(l)

Explanation:

(A) As we know that HCl is a strong acid and when it is added to an aqueous solution then it leads to increase in the concentration of hydrogen ions. And, when an acid or base is added to a solution then any resistance by the solution in changing the pH of the solution is known as a buffer.

This means that addition of buffer into the given solution will not cause much change in the concentration of H_{3}O^{+} in large amount.

As both the buffer components are salt then they will remain dissociated as follows.

       Na_{2}HPO_{4}(aq) \rightarrow 2Na^{+}(aq) + HPO^{2-}_{4}(aq)

 NaH_{2}PO_{4}(aq) \rightarrow Na^{+}(aq) + H_{2}PO^{-}_{4}(aq)

Hence, net ionic equation will be as follows.

       H_{3}O^{+}(aq) + HPO^{2-}_{4}(aq) \rightarrow H_{2}PO^{2-}_{4}(aq) + H_{2}O(l)

(B)  When we add small amount of sodium hydroxide into the solution then there will occur an increase in concentration of hydroxide ions into the solution. But then due to the presence of buffer there will occur not much change in concentration and the acid will get converted into salt.

     NaOH(aq) \rightarrow Na^{+}(aq) + OH^{-}(aq)

The net ionic equation is as follows.

        H_{2}PO^{-}_{4}(aq) + OH^{-}(aq) \rightarrow HPO^{2-}_{4}(aq) + H_{2}O(l)

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3 years ago
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