The best answer for the question above would be the chloroflourocarbons or the CFCs. These chloroflourocarbons or CFCs are the ones responsible for the depletion of the ozone - which leads to leaving a hole in its layer. These gases eat out the ozone layer and allows harmful UV rays of the sun to come in the Earth.
Since obliquity is the angle between the axis of rotation and the direction perpendicular to the orbital plane, it changes as the orbital plane changes due to the influence of other planets. But the axis of rotation can also move (axial precession), due to torque exerted by the sun on a planet's equatorial bulge. (Got it from google )
