Alkenes on reaction with meta-chloroperoxybenzoic acid (MCPBA ) produces epoxides. When styrene is reacted with mCPBA it gives 2-phenyloxirane as shown below,
Answer:
0.967mole
Explanation:
Given parameters:
Volume of NH₄Cl = 21.67L
Unknown:
Number of moles = ?
Solution:
We assume that the volume was taken at standard temperature and pressure,
Then;
Number of moles = 
Number of moles = 
= 0.967mole
There are three subatomic particles known: (1) electron which is found outside the nucleus of an atom and (2 and 3) protons and neutrons which are both inside the nucleus. As they are outside the nucleus, it is easier to transport electron than any other subatomic particle. Thus, atom and its ion differ in the number of electrons.
Using the Henderson-Hasselbalch equation on the solution before HCl addition: pH = pKa + log([A-]/[HA]) 8.0 = 7.4 + log([A-]/[HA]); [A-]/[HA] = 4.0. (equation 1) Also, 0.1 L * 1.0 mol/L = 0.1 moles total of the compound. Therefore, [A-] + [HA] = 0.1 (equation 2) Solving the simultaneous equations 1 and 2 gives: A- = 0.08 moles AH = 0.02 moles Adding strong acid reduces A- and increases AH by the same amount. 0.03 L * 1 mol/L = 0.03 moles HCl will be added, soA- = 0.08 - 0.03 = 0.05 moles AH = 0.02 + 0.03 = 0.05 moles Therefore, after HCl addition, [A-]/[HA] = 0.05 / 0.05 = 1.0 Resubstituting into the Henderson-Hasselbalch equation: pH = 7.4 + log(1.0) = 7.4, the final pH.
