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dmitriy555 [2]
3 years ago
15

What acid chloride would be needed to prepare the following ketone from benzene using a Friedel-Crafts acylation? Click the "dra

w structure" button to launch the drawing utility.

Chemistry
1 answer:
Paraphin [41]3 years ago
3 0

Answer:

                    Benzoyl Chloride

Explanation:

                     Friedel-Craft Acylation is reaction utilized to add electrophiles (particularly carbonyl group) across double bonds of aromatic compounds.

In given case benzophenone is synthesized using benzene and benzoyl chloride.

Mechanism:

Step 1: In first step benzoyl chloride is treated with lewis acid to generate an electrophile i.e. oxo(phenyl)methylium.

Step 2: In the second step benzene undergoes electrophilic substitution reaction and adds the electrophile.

Step 3: In last step the aromaticity of benzene is restored with the elimination of proton.

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Marizza181 [45]

Answer:

\Delta _rH=-1124.14kJ/mol

Explanation:

Hello!

In this case, since the standard enthalpy change for a chemical reaction is stood for the enthalpy of reaction, for the given reaction:

2H_2S(g) +3O_2(g)\rightarrow 2H_2O(l) +2SO_2(g)

We set up the enthalpy of reaction considering the enthalpy of formation of each species in the reaction at the specified phase and the stoichiometric coefficient:

\Delta _rH=2\Delta _fH_{H_2O,liq}+2\Delta _fH_{SO_2,gas}-2\Delta _fH_{H_2S,gas}-3\Delta _fH_{O_2,gas}

In such a way, by using the NIST database, we find that:

\Delta _fH_{H_2O, liq}=-285.83kJ/mol\\\\\Delta _fH_{SO_2, gas}=-296.84kJ/mol\\\\\Delta _fH_{O_2,gas}=0kJ/mol\\\\\Delta _fH_{H_2S,gas}=-20.50kJ/mol

Thus, we plug in the enthalpies of formation to obtain:

\Delta _rH=2(-285.73kJ/mol)+2(-296.84kJ/mol)-2(-20.50kJ/mol)-3(0kJ/mol)\\\\\Delta _rH=-1124.14kJ/mol

Best regards!

8 0
3 years ago
A jar is filled with water, and the lid is closed tightly. The jar is kept at constant temperature. What happens at the surface
Katarina [22]
<h2>Hello!</h2>

The correct answer is A: Water molecules evaporate and condense at the same rate.

<h2>Why?</h2>

Evaporation is defined as the physical change from liquid to gas, and Condensation is the physical change from gas to liquid.

At any given temperature, these two processes occur at once, in a dynamic equilibrium.

When the lid is closed, evaporation occurs faster than condensation, and pressure increases. Then, when pressure reaches a critical value, condensation starts to occur faster than evaporation, until an equilibrium is reached, and the pressure of the water molecules in the gas phase is maximum for that temperature. The pressure at that point is called Vapor Pressure.

Have a nice day!

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your answer is c. two atoms of oxygen.

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A change in temperature is evidence of a chemical reaction.

Also: They are chemicals...

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