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dlinn [17]
3 years ago
10

A cylinder containing 20.0 L of compressed nitrogen is connected to an empty (evacuated) vessel with an unknown volume. The gas

pressure in the cylinder starts at 25 atm and drops to 2 atm without a change in temperature. Determine the volume of the vessel.
Chemistry
1 answer:
Nonamiya [84]3 years ago
3 0

Answer:

The new volume of the vessel is 250 L

Explanation:

Step 1: Data given

The volume of the cylinder = 20.0 L

The initial pressure of the gas = 25 atm

The pressure drops to 2 atm

Step 2: Calculate the volume of the vessel

P1*V1 = P2*V2

⇒with P1 = the initial pressure = 25 atm

⇒with V1 = the initial volume = 20.0 L

⇒with P2 = the final pressure = 2 atm

⇒with V2 = the final volume = TO BE DETERMINED

25 atm* 20.0 L = 2.0 atm * V2

V2 = 250 L

The new volume of the vessel is 250 L

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how to determine the net charge of the tripeptide Asp-Gly-Leu at pH 7. Can someone show in details and tricks on how to solve it
Ugo [173]

Answer:

0!

Explanation:

  • You need to search your pKa values for Asn (2.14, 8.75), Gly (2.35, 9.78) and Leu(2.33, 9.74), the first value corresponding to -COOH, the second to -NH3 (a third value would correspond to an R group, but in this case that does not apply), and we'll build a table to find the charges for your possible dissociated groups at indicated pH (7), we need to remember that having a pKa lower than the pH will give us a negative charge, having a pKa bigger than pH will give us a positive charge:            

           

                   -COOH         -NH3              

pH 7------------------------------------------------------              

Asn               -                      +

Gly                -                      +

Leu               -                      +

  • Now that we have our table we'll sketch our peptide's structure:

<em>HN-Asn-Gly-Leu-COOH</em>

This will allow us to see what groups will be free to react to the pH's value, and which groups are not reacting to pH because are forming the bond between amino acids. In this particular example only -NH group in Ans and -COOH in Leu are exposed to pH, we'll look for these charges in the table and add them to find the net charge:

+1 (HN-Asn)

-1 (Leu-COOH)

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The net charge is 0!

I hope you find this information useful and interesting! Good luck!

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3 years ago
Write the fraction of the mass of kcl produced from 1 g of k2c03​
Minchanka [31]

Mass of KCl= 1.08 g

<h3>Further explanation</h3>

Given

1 g of K₂CO₃

Required

Mass of KCl

Solution

Reaction

K₂CO₃ +2HCl ⇒ 2KCl +H₂O + CO₂

mol of K₂CO₃(MW=138 g/mol) :

= 1 g : 138 g/mol

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From the equation, mol ratio K₂CO₃ : KCl = 1 : 2, so mol KCl :

= 2/1 x mol K₂CO₃

= 2/1 x 0.00725

= 0.0145

Mass of KCl(MW=74.5 g/mol) :

= mol x MW

= 0.0145 x 74.5

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