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3 years ago

Scientific endeavor must be driven by the needs of society and not by simple curiosity. true false

Chemistry

1 answer:

vazorg [7]3 years ago

5 0

False people can do whatever they want without people telling them what to do.

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From the value Kf=1.2×109 for Ni(NH3)62+, calculate the concentration of NH3 required to just dissolve 0.016 mol of NiC2O4 (Ksp

Nina [5.8K]

Answer: The concentration of $NH_3$ required will be 0.285 M.

Explanation:

To calculate the molarity of $NiC_2O_4$ , we use the equation:

$\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}$

Moles of $NiC_2O_4$ = 0.016 moles

Volume of solution = 1 L

Putting values in above equation, we get:

$\text{Molarity of }NiC_2O_4=\frac{0.016mol}{1L}=0.016M$

For the given chemical equations:

$NiC_2O_4(s)\rightleftharpoons Ni^{2+}(aq.)+C_2O_4^{2-}(aq.);K_{sp}=4.0\times 10^{-10}$

$Ni^{2+}(aq.)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K_f=1.2\times 10^9$

Net equation: $NiC_2O_4(s)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K=?$

To calculate the equilibrium constant, K for above equation, we get:

$K=K_{sp}\times K_f\\K=(4.0\times 10^{-10})\times (1.2\times 10^9)=0.48$

The expression for equilibrium constant of above equation is:

$K=\frac{[C_2O_4^{2-}][[Ni(NH_3)_6]^{2+}]}{[NiC_2O_4][NH_3]^6}$

As, $NiC_2O_4$ is a solid, so its activity is taken as 1 and so for $C_2O_4^{2-}$

We are given:

$[[Ni(NH_3)_6]^{2+}]=0.016M$

Putting values in above equations, we get:

$0.48=\frac{0.016}{[NH_3]^6}}$

$[NH_3]=0.285M$

Hence, the concentration of $NH_3$ required will be 0.285 M.

7 0

3 years ago

What is the half-life of an isotope that decays to 6.25% of its original activity in 18.9 hours?

inessss [21]

Radioactive material obeys 1st order decay kinetics,
For 1st order reaction, we have
k = $\frac{2.303}{t}Xlog \frac{\text{initial conc.}}{\text{final conc.}}$
where, k = rate constant of reaction

Given: Initial conc. 100, Final conc. = 6.25, t = 18.9 hours

∴ k = $\frac{2.303}{18.9} X log \frac{100}{6.25}$ = 0.1467 hours^(-1)

Now, for 1st order reactions: half life = $\frac{0.693}{k} = \frac{0.693}{0.1467}$ = 4.723 hours.

8 0

3 years ago

how many particles of the part that orbits the nucleus is on the shell closest to the center of the atom?

kolezko [41]

There are 2 atoms orbiting it.

8 0

3 years ago

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How much heat is required to raise the temperature of 50.0g of water 13°C

N76 [4]

Answer:one gram by 1oC

Explanation: you will need to know the value of water's specific heat