Answer:
The molecular formula of the compound :
Explanation:
The empirical formula of the compound =
The molecular formula of the compound =
The equation used to calculate the valency is :
We are given:
Mass of molecular formula = 86 g/mol
Mass of empirical formula = 43 g/mol
Putting values in above equation, we get:
The molecular formula of the compound :
M=11.20 g
m(H₂)=0.6854 g
M(H₂)=2.016 g/mol
M(Mg)=24.305 g/mol
M(Zn)=65.39 g/mol
w-?
m(Mg)=wm
m(Zn)=(1-w)m
Zn + 2HCl = ZnCl₂ + H₂
m₁(H₂)=M(H₂)m(Zn)/M(Zn)=M(H₂)(1-w)m/M(Zn)
Mg + 2HCl = MgCl₂ + H₂
m₂(H₂)=M(H₂)m(Mg)/M(Mg)=M(H₂)wm/M(Mg)
m(H₂)=m₁(H₂)+m₂(H₂)
m(H₂)=M(H₂)(1-w)m/M(Zn)+M(H₂)wm/M(Mg)=M(H₂)m{(1-w)/M(Zn)+w/M(Mg)}
m(H₂)=M(H₂)m{(1-w)/M(Zn)+w/M(Mg)}
(1-w)/M(Zn)+w/M(Mg)=m(H₂)/{M(H₂)m}
1/M(Zn)-w/M(Zn)+w/M(Mg)=m(H₂)/{M(H₂)m}
w(1/M(Mg)-1/M(Zn))=m(H₂)/{M(H₂)m}-1/M(Zn)
w=[m(H₂)/{M(H₂)m}-1/M(Zn)]/(1/M(Mg)-1/M(Zn))
w=0.583 (58.3%)
Na = +1
H = +1
O = -2
Total charge is 0:
1 + 1 + C + 3 x -2 = 0
C = 4
Answer:
A reaction is non-spontaneous at any temperature when the Gibbs free energy > 0.
Explanation:
There is a state function, that determines if a reaction is sponaneous or non spontaneous:
ΔG = Gibbs free energy
A reaction is non spontaneous when it does require energy to produce that reaction. It will be spontaneous, when the reaction does not require energy to be occured.
The formula is: ΔG = ΔH - T.ΔS
ΔH → Enthalpy → Energy gained or realeased as heat.
ΔH < 0 → <em>Exothermic reaction. Spontaneity is favored
</em>
T → Temperature
ΔS → Entropy → Degree of disorder of a system.
When the system has a considered disorder ΔS > 0, disorder increases.
When the system is more ordered, ΔS < 0, disorder decreases.
The reaction will be non spontaneous if, the enthalpy is positive (endothermic reaction) and the ΔS < 0 (disorder decreases). It will not occur if we do not give energy.
ΔG < 0 → Spontaneous reaction
ΔG > 0 → Non spontaneous reaction
ΔG = 0 → System in equilibrium
