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rusak2 [61]
4 years ago
7

Two Carnot engines are operated in series with the exhaust (heat output) of the first engine being the input of the second engin

e. The upper temperature of this combination is 260F, the lower temperature is 40F. If each engine has the same thermal efficiency, determine the exhaust temperature of the first engine (the inlet temperature of the second engine). Ans: T = 140F 3. A nuclear power plant generates 750 MW of power. The heat engine uses a nuclear reactor operating at 315C as the source of heat. A river is available (at 20C) which has a volumetric flow rate of 165 m/s. If you use the river as a heat sink, estimate the temperature rise in the river at the point where the heat is dumped. Assume the actual efficiency of the plant is 60% of the Carnot efficiency.
Chemistry
1 answer:
OlgaM077 [116]4 years ago
8 0

Answer:

(a) 140 F

(b) The temperature rise at the point where the heat is dumped is 2.51 degC

Explanation:

(a) Considering T1 the temperature of input of the first engine, T2 the temperature of the exhaust of the first engine (and input of the second engine) and T3 the exhaust of the second engine, if both engines have the same efficiency we have:

\eta=1-\frac{T_1}{T2}=1-\frac{T_2}{T_3}

The temperatures have to be expressed in Rankine (or Kelvin) degrees

1-\frac{T_1}{T2}=1-\frac{T_2}{T_3}\\\\\frac{T_1}{T2}=\frac{T_2}{T_3}\\\\(T_2)^{2} =T_1*T_3\\\\T_2=\sqrt{T_1*T_3} =\sqrt{(459.67+260)*(459.67+40)}= \sqrt{719.67*499.67}\\\\ T_2=599 \, R= (599-459.67) ^{\circ} F=140^{\circ} F

(b) The Carnot efficiency of the cycle is

\eta_{c}=1-Th/Ts=1-(273+20)/(273+315)=0.502

If the efficiency of the plant is 60% of the Carnot efficiency, we have

\eta=0.6*\eta_{c}=0.6*0.502=0.302

The heat used in the plant can be calculated as

Q_i=W/\eta=750MW/0.302=2483MW

And the heat removed to the heat sink is

Q_o=Qi-W=2483-750=1733MW

If the flow of the river is 165 m3/s, the heat per volume in the sink is

\frac{Q_o}{f} =\frac{1733 MJ/s}{165 m3/s}= 10.5MJ/m3

Considering a heat capacity of water C=4.1796 kJ/(kg*K) and a density ρ of 1000 kg/m3, the temperature rise of the water is

\Delta Q=C*\Delta T\\\Delta T=(1/C)*\Delta Q\\\Delta T=(\frac{1}{4.1796\frac{kJ}{kgK} } )*10,500\frac{kJ}{m3}*\frac{1m3}{1000kg}\\\Delta T= 2.51 ^{\circ}C

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3 years ago
Caffeine, a stimulant in coffee and tea, has a molar mass of 194.19 g/mol and a mass percentage composition of 49.48% C, 5.19% H
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Answer : The molecular formula of a caffeine is, C_8H_{10}N_4O_2

Solution :

If percentage are given then we are taking total mass is 100 grams.

So, the mass of each element is equal to the percentage given.

Mass of C = 49.48 g

Mass of H = 5.19 g

Mass of N = 28.85 g

Mass of O = 16.48 g

Molar mass of C = 12 g/mole

Molar mass of H = 1 g/mole

Molar mass of N = 14 g/mole

Molar mass of O = 16 g/mole

Step 1 : convert given masses into moles.

Moles of C = \frac{\text{ given mass of C}}{\text{ molar mass of C}}= \frac{49.48g}{12g/mole}=4.12moles

Moles of H = \frac{\text{ given mass of H}}{\text{ molar mass of H}}= \frac{5.19g}{1g/mole}=5.19moles

Moles of N = \frac{\text{ given mass of N}}{\text{ molar mass of N}}= \frac{28.85g}{14g/mole}=2.06moles

Moles of O = \frac{\text{ given mass of O}}{\text{ molar mass of O}}= \frac{16.48g}{16g/mole}=1.03moles

Step 2 : For the mole ratio, divide each value of moles by the smallest number of moles calculated.

For C = \frac{4.12}{1.03}=4

For H = \frac{5.19}{1.03}=5.03\approx 5

For N = \frac{2.06}{1.03}=2

For O = \frac{1.03}{1.03}=1

The ratio of C : H : N : O = 4 : 5 : 2 : 1

The mole ratio of the element is represented by subscripts in empirical formula.

The Empirical formula = C_4H_5N_2O_1=C_4H_5N_2O

The empirical formula weight = 4(12) + 5(1) + 2(14) + 16 = 97 gram/eq

Now we have to calculate the molecular formula of the compound.

Formula used :

n=\frac{\text{Molecular formula}}{\text{Empirical formula weight}}

n=\frac{194.19}{97}=2

Molecular formula = (C_4H_5N_2O)_n=(C_4H_5N_2O)_2=C_8H_{10}N_4O_2

Therefore, the molecular of the caffeine is, C_8H_{10}N_4O_2

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If you only have a few scientists working on a question, it will take longer to find an answer. With more people working on a concept, it can be solved in more time.

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