UV spectroscopy measures the energy required to promote an electron from the ________ molecular orbital to the ________ molecula
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Since the addition of the H2O in the last step of hydroboration is anti-Markovnikov, the starting material is 1-pentyne.
The addition of H2 to C5H8 yields an alkene when a Lindlar catalyst is used. Recall that the Lindlar catalysts poisons the process so that the addition do not go on to produce an alkane.
When hydroboration is carried out on the alkene, we are told that a primary alcohol was obtained. We must note that in the last step of hydroboration, water is added in an anti- Markovnikov manner to yield the primary alcohol. Hence, the starting material must be 1-pentyne as shown in the image attached.
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Answer: The theoretical yield of 4-nitrochalcone is,
Explanation : Given,
Volume of acetophenone = 135 microliters = 135 × 10⁻⁶ L = 0.135 mL
conversion used : (1 microliter = 10⁻⁶ L) and (1 L = 1000 mL)
Density of acetophenone = 1.03 g/mL
Mass of acetophenone = Density × Volume = 1.03 g/mL × 0.135 mL = 0.139 g
Mass of 4-nitrobenzaldehyde = 127 mg = 0.127 g
Conversion used : (1 mg = 0.001 g)
First we have to calculate the moles of acetophenone and 4-nitrobenzaldehyde
and,
Now we have to calculate the limiting and excess reagent.
The balanced chemical equation is:
From the balanced reaction we conclude that
As, 1 mole of 4-nitrobenzaldehyde react with 1 mole of acetophenone
So, 0.000840 mole of 4-nitrobenzaldehyde react with 0.000840 mole of acetophenone
From this we conclude that, acetophenone is an excess reagent because the given moles are greater than the required moles and 4-nitrobenzaldehyde is a limiting reagent and it limits the formation of product.
Now we have to calculate the moles of 4-nitrochalcone
From the reaction, we conclude that
As, 1 mole of 4-nitrobenzaldehyde react to give 1 mole of 4-nitrochalcone
So, 0.000840 mole of 4-nitrobenzaldehyde react to give 0.000840 mole of 4-nitrochalcone
Now we have to calculate the mass of 4-nitrochalcone
Molar mass of 4-nitrochalcone = 253.25 g/mole
(1 g = 1000 g)
Therefore, the theoretical yield of 4-nitrochalcone is,