Answer:
Less
Explanation:
Since [Cu(NH3)4]2+ and [Cu(H2O)6]2+ are Octahedral Complexes the transitions between d-levels explain the majority of the absorbances seen in those chemical compounds. The difference in energy between d-levels is known as ΔOh (ligand-field splitting parameter) and it depends on several factors:
- The nature of the ligand: A spectrochemical series is a list of ligands ordered on ligand strength. With a higher strength the ΔOh will be higher and thus it requires a higher energy light to make the transition.
- The oxidation state of the metal: Higher oxidation states will strength the ΔOh because of the higher electrostatic attraction between the metal and the ligand
A partial spectrochemical series listing of ligands from small Δ to large Δ:
I− < Br− < S2− < Cl− < N3− < F−< NCO− < OH− < C2O42− < H2O < CH3CN < NH3 < NO2− < PPh3 < CN− < CO
Then NH3 makes the ΔOh higher and it requires a higher energy light to make the transition, which means a shorter wavelength.
The gas laws describe and predict the behavior of gases with an explanation and experimental data
So the given statement is False.
2) The volume of gas can be calculated based on Avagadro's law
It states that the volume of a gas is directly proportional or varies with the moles of the gas. Higher the moles more the volume, condition is the pressure and temperature are constants in the two conditions
Thus as here the pressure and temperature of nitrogen gas is kept constant
V α moles
or
Where
V1 = 6 l
n1 = 0.50 mol
V2 = ?
n2 = 0.75 mol
On putting values
V2 = 6 X 0.75 / 0.5 = 9 L
so resulting volume of the gas will be 9L
It could not hold good for elements heaver than calcium.
