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Suppose you have just added 100 ml of a solution containing 0.5 mol of acetic acid per liter to 400 ml of 0.5 m naoh. what is th

Tpy6a [65]

$pH = 13.5$

Explanation:

Sodium hydroxide completely ionizes in water to produce sodium ions and hydroxide ions. Hydroxide ions are in excess and neutralize all acetic acid added by the following ionic equation:

$\text{HAc} + \text{OH}^{-} \to \text{Ac}^{-} + \text{H}_2\text{O}$

The mixture would contain

$0.4 \times 0.5 - 0.1 \times 0.5 = 0.15 \; \text{mol}$ of $\text{OH}^{-}$ and
$0.1 \times 0.5 = 0.05 \; \text{mol}$ of $\text{Ac}^{-}$

if $\text{Ac}^{-}$ undergoes no hydrolysis; the solution is of volume $0.1 + 0.4 = 0.5 \; \text{L}$ after the mixing. The two species would thus be of concentration $0.30 \; \text{mol} \cdot \text{L}^{-1}$ and $0.10 \; \text{mol} \cdot \text{L}^{-1}$ , respectively.

Construct a RICE table for the hydrolysis of $\text{Ac}^{-}$ under a basic aqueous environment (with a negligible hydronium concentration.)

$\begin{array}{cccccccc} \text{R} & \text{Ac}^{-}(aq) &+ & \text{H}_2\text{O}(aq) & \leftrightharpoons & \text{HAc}(aq) & + & \text{OH}^{-} (aq)\\ \text{I} & 0.10 \; \text{M} & & & & & &0.30 \; \text{M}\\ \text{C} & -x \; \text{M}& & & & +x \; \text{M}& & +x \; \text{M} \\ \text{E} & (0.10 - x) \; \text{M} & & & & x \; \text{M} & & (0.30 +x) \; \text{M} \end{array}$

The question supplied the <em>acid</em> dissociation constant $pK_a$ for acetic acid $\text{HAc}$ ; however, calculating the hydrolysis equilibrium taking place in this basic mixture requires the <em>base</em> dissociation constant $pK_b$ for its conjugate base, $\text{Ac}^{-}$ . The following relationship relates the two quantities:

$pK_{b} (\text{Ac}^{-}) = pK_{w} - pK_{a}( \text{HAc})$

... where the water self-ionization constant $pK_w \approx 14$ under standard conditions. Thus $pK_{b} (\text{Ac}^{-}) = 14 - 4.7 = 9.3$ . By the definition of $pK_b$ :

$[\text{HAc} (aq)] \cdot [\text{OH}^{-} (aq)] / [\text{Ac}^{-} (aq) ] = K_b = 10^{-pK_{b}}$

$x \cdot (0.3 + x) / (0.1 - x) = 10^{-9.3}$

$x = 1.67 \times 10^{-10} \; \text{M} \approx 0 \; \text{M}$

$[\text{OH}^{-}] = 0.30 +x \approx 0.30 \; \text{M}$

$pH = pK_{w} - pOH = 14 + \text{log}_{10}[\text{OH}^{-}] = 14 + \text{log}_{10}{0.30} = 13.5$

6 0

3 years ago

Upon balancing the equation below, how many moles of sulfuric acid are needed to react completely with 8.4 moles of lithium hydr

maks197457 [2]

The answer is b. 4.2 mole. The balanced reaction formula is 2LiOH + H2SO4 -->Li2SO4 + 2H2O. And the ratio of mole number of the reactants is the same as the ratio of coefficients.

7 0

3 years ago

Gizmo Warm-up

Mariana [72]

Sodium hydroxide solution and hydrogen gas are produced from the reaction of water and sodium.

<h2>Reaction of sodium and water</h2>

We observe bubbles coming out of the water when the sodium reacts with the water because of the formation of hydrogen gas which is insoluble in water so it moves into the atmosphere.

<h3>Products of the reaction</h3>

Sodium metal reacts rapidly with water to form sodium hydroxide (NaOH) solution and hydrogen gas (H2). This chemical reaction is exothermic because huge amount of heat is release from the solution so we can conclude that sodium hydroxide solution and hydrogen gas are produced from the reaction of water and sodium.

Learn more about chemical reaction here: brainly.com/question/26018275

Learn more: brainly.com/question/26167984

8 0

2 years ago

How many atoms of oxygen are represented in 2CaNO3?

MrRissso [65]

Answer:

6 atoms of oxygen

Explanation:

8 0

3 years ago

HELP IT’S ABOUT TO BE DUE!

Vinil7 [7]

The answer is b
Explanation:

7 0

3 years ago