1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
mestny [16]
3 years ago
6

A 25.0 mL sample of 0.100 M pyridine (Kb for pyridine is 1.7 ✕ 10-9) is titrated with 0.100 M HCl solution. Calculate the pH aft

er the addition of the following amounts of HCl with sig figs. a) 24.5 mL b) 25.0 mL c) 26.0 mL d) 28.0 mL e) 30.0 mL
Chemistry
1 answer:
Alborosie3 years ago
3 0

Answer:

a) pH = 3.54

b) pH =  3.27

c) pH = 2.71

d) pH = 2.25

e) pH = 2.04

Explanation:

Step 1: Data given

Volume of a 0.100 M pyridine solution = 25.0 mL = 0.025 L

Kb for pyridine is 1.7 * 10^-9

Molarity of HCl = 0.100 M

Step 2: The balanced equation

C5H5N(aq) + HCl (aq) → C5H5NH+ +Cl-(aq)

Step 3: Calculate moles

Moles pyridine = Molarity pyridine * volume

Moles pyridine = 0.100 M * 0.025 L

Moles pyridine = 0.0025 moles

Moles HCl = 0.100 M * 0.0245 L

Moles HCl = 0.00245 moles

Step 4: Calculate the limiting reactant

For 1 mol pyridine we need 1 mol HCl to produce 1 mol C5H5NH+

HCl is the limiting reactant. It will completely be consumed (0.00245 moles). Pyridine is in excess. There will react 0.00245 moles. There will remain 0.0025 - 0.00245 = 0.00005 moles

There will be produce 0.00245 moles C5H5NH+

Step 5: Calculate the molarity

Molarity = moles / volume

Molarity C5H5N = 0.00005 moles / 0.0495 L

Molarity C5H5N = 0.00101 M

Molarity C5H5NH+ = 0.00245 moles / 0.0495 L

Molarity C5H5NH+ = 0.0495 M

Step 6: Calculate pOH

pOH = pKb + log ([B+]/[BOH])

pOH = 8.77 + log (0.0495 / 0.00101)

pOH = 10.46

Step 7: Calculate pH

pH = 14 - 10.46 = 3.54

When adding 25.0 mL HCl

Moles pyridine = Molarity pyridine * volume

Moles pyridine = 0.100 M * 0.025 L

Moles pyridine = 0.0025 moles

Moles HCl = 0.100 M * 0.025 L

Moles HCl = 0.0025 moles

Step 4: Calculate the limiting reactant

For 1 mol pyridine we need 1 mol HCl to produce 1 mol C5H5NH+

Both HCl and pyridine will completely be consumed.  

The total volume now is 25.0 mL + 25.0 mL = 50.0 so the concentration of the C5H5NH+ to start is 0.0025 moles / 0.05 L = 0.05 M

C5H5NH+ + H2O ==> C5H5N + H3O^+

The concentration of C5H5NH+ will be 0.05 - X M

The concentration of C5H5N and H2O will be X

Ka = K/ Kb

Ka = X²/ (0.05 -X)

X = [H3O+] = 0.000542

pH = -log (0.000542)

pH = 3.27

When adding 26.0 mL HCl

Moles pyridine = Molarity pyridine * volume

Moles pyridine = 0.100 M * 0.025 L

Moles pyridine = 0.0025 moles

Moles HCl = 0.100 M * 0.026 L

Moles HCl = 0.0026 moles

Step 4: Calculate the limiting reactant

For 1 mol pyridine we need 1 mol HCl to produce 1 mol C5H5NH+

Pyridine is the limiting reactant. All of it will be consumed.

There will remain 0.0001 mol HCl

Step 5: Calculate pH of HCl

pH = -log [H+]

pH = -log (0.0001 / 0.051 L)

pH = -log ( 0.00196)

pH = 2.71

When adding 28.0 mL HCl

Moles pyridine = Molarity pyridine * volume

Moles pyridine = 0.100 M * 0.025 L

Moles pyridine = 0.0025 moles

Moles HCl = 0.100 M * 0.028 L

Moles HCl = 0.0028 moles

Step 4: Calculate the limiting reactant

For 1 mol pyridine we need 1 mol HCl to produce 1 mol C5H5NH+

Pyridine is the limiting reactant. All of it will be consumed.

There will remain 0.0003 mol HCl

Step 5: Calculate pH of HCl

pH = -log [H+]

pH = -log (0.0003 / 0.053 L)

pH = -log ( 0.00566)

pH = 2.25

When adding 30.0 mL HCl

Moles pyridine = Molarity pyridine * volume

Moles pyridine = 0.100 M * 0.025 L

Moles pyridine = 0.0025 moles

Moles HCl = 0.100 M * 0.030 L

Moles HCl = 0.0030 moles

Step 4: Calculate the limiting reactant

For 1 mol pyridine we need 1 mol HCl to produce 1 mol C5H5NH+

Pyridine is the limiting reactant. All of it will be consumed.

There will remain 0.0005 mol HCl

Step 5: Calculate pH of HCl

pH = -log [H+]

pH = -log (0.0005 / 0.055 L)

pH = -log ( 0.00909)

pH = 2.04

You might be interested in
B. How do you think the physical properties (strength, flexibility, and viscosity) of the polymer would change if more borate ha
Talja [164]

It became thicker and its viscosity decreased and cannot flow as easily as before.

You ignite a chemical reaction by adding the borax solution to the glue mixture.

In a chemical reaction, the molecules of glue and borax combine to form a flexible, springy new substance. With rubber's vulcanization serving as a model, chemical cross-linking has been extensively employed to change the physical properties of polymeric materials.

Chemical links between polymer chains provide a substance with a more solid structure and perhaps a better-defined shape. It thickened and lost viscosity, making it more difficult to flow than it once could.

Learn more about the chemical reaction  here brainly.com/question/16714866

#SPJ4.

3 0
1 year ago
Is Carbon combustible? Why or why not?
valkas [14]
Carbon is not combustible because when it combines with oxygen its energy increases thus it doesnt combust. 
3 0
3 years ago
A point of reference is anything that seems steady that is used compare the position of an object
Masja [62]

Answer:

True

Explanation:

hope it'll help!!

4 0
3 years ago
Read 2 more answers
Determine the mass of copper that has the same number of atoms as there are in 6.95 mg of potassium. Answer in units of mg.
Naya [18.7K]
Do you have a reference table?
5 0
3 years ago
Scientists think the moon was formed when
lubasha [3.4K]

Answer:

A meteor hit earth they think the moon is created from debris from earth but really God created it UwU

Explanation:

5 0
3 years ago
Other questions:
  • What amount of heat will raise the temperature of 78g liquid water from 20 C to 80 C?
    14·1 answer
  • In the reaction Mg (s) + 2HCl (aq) H2 (g) + MgCl2 (aq), how many liters of hydrogen gas will be produced from 75.0 milliliters o
    13·1 answer
  • A single atom of an element has 11 protons, 11 electrons, and 12 neutrons. Which element is it?
    10·1 answer
  • WHAT DID YOU OBSERVE HAPPENED WHEN AN S-WAVE TRAVELED INTO A LIQUID?
    9·1 answer
  • What pressure will be exerted by 0.57 moles of CO2 at a temperature of 25°C and a volume of 500 ML? _____atm
    15·1 answer
  • What is the pH of a solution whose hydronium concentration is 3.5 x 10^(-3) M?<br><br> Thanks!
    10·1 answer
  • Consider an experimental setup with two compartments separated by a phospholipid bilayer membrane containing ion channels select
    11·1 answer
  • What’s the answer ?
    13·2 answers
  • In the lab, you are given a metal ball. You measure the mass of the ball to be 28 g. You place the ball in a graduated cylinder
    12·1 answer
  • Kingdom:
    15·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!