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3 years ago

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If 0.255 moles of AgNO₃ react with 0.155 moles of H₂SO₄ according to this UNBALANCED equation below, how many grams of Ag₂SO₄ co

uld be formed? AgNO₃(aq) + H₂SO₄ (aq) → Ag₂SO₄ (s) + HNO₃ (aq)

1 answer:

Ber [7]3 years ago

4 0

Answer: 6.162g of Ag2SO4 could be formed

Explanation:

Given;

0.255 moles of AgNO3

0.155 moles of H2SO4

Balanced equation will be given as;

2AgNO3(aq) + H2SO4(aq) -> Ag2SO4(s) + 2HNO3(aq)

Seeing that 2 moles of AgNO3 is required to react with 1 moles of H2SO4 to produce 1 mole of Ag2SO4,

Therefore the number of moles of Ag2SO4 produced is given by,

n(Ag2SO4) = 0.255 mol of AgNO3 ×

[0.155mol H2SO4 ÷ 2 mol AgNO3] x

[ 1 mol Ag2SO4 ÷ 1 mol H2SO4]

= 0.0198 mol of Ag2SO4.

mass = no of moles x molar mass

From literature, molar mass of Ag2SO4 = 311.799g/mol.

Thus,

Mass = 0.0198 x 311.799

= 6.162g

Therefore, 6.162g of Ag2SO4 could be formed

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Construct a RICE table for the hydrolysis of $\text{Ac}^{-}$ under a basic aqueous environment (with a negligible hydronium concentration.)

$\begin{array}{cccccccc} \text{R} & \text{Ac}^{-}(aq) &+ & \text{H}_2\text{O}(aq) & \leftrightharpoons & \text{HAc}(aq) & + & \text{OH}^{-} (aq)\\ \text{I} & 0.10 \; \text{M} & & & & & &0.30 \; \text{M}\\ \text{C} & -x \; \text{M}& & & & +x \; \text{M}& & +x \; \text{M} \\ \text{E} & (0.10 - x) \; \text{M} & & & & x \; \text{M} & & (0.30 +x) \; \text{M} \end{array}$

The question supplied the <em>acid</em> dissociation constant $pK_a$ for acetic acid $\text{HAc}$ ; however, calculating the hydrolysis equilibrium taking place in this basic mixture requires the <em>base</em> dissociation constant $pK_b$ for its conjugate base, $\text{Ac}^{-}$ . The following relationship relates the two quantities:

$pK_{b} (\text{Ac}^{-}) = pK_{w} - pK_{a}( \text{HAc})$

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