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Arlecino [84]
3 years ago
8

In a chemical reaction, the difference between the potential energy of the products of the potential energy of the reactants is

equal to the .
a)activation energy .
b)entropy of the system.
c)heat of fusion.
d)activation energy
Chemistry
1 answer:
natka813 [3]3 years ago
3 0
In a chemical reaction, the difference between the potential energy of the products and the potential energy of the reactants is equal to the heat of the reaction<span>. This is, the net energy released or absorbed (change) during a chemical reaction is the sum of the potential energy of the products less the sum of the potential energy of the reactants.</span>
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CO2(g)+CCl4(g)⇌2COCl2(g) Calculate ΔG for this reaction at 25 ∘C under these conditions: PCO2PCCl4PCOCl2===0.140 atm0.185 atm0.7
padilas [110]

<u>Answer:</u> The \Delta G for the reaction is 54.425 kJ/mol

<u>Explanation:</u>

For the given balanced chemical equation:

CO_2(g)+CCl_4(g)\rightleftharpoons 2COCl_2(g)

We are given:

\Delta G^o_f_{CO_2}=-394.4kJ/mol\\\Delta G^o_f_{CCl_4}=-62.3kJ/mol\\\Delta G^o_f_{COCl_2}=-204.9kJ/mol

To calculate \Delta G^o_{rxn} for the reaction, we use the equation:

\Delta G^o_{rxn}=\sum [n\times \Delta G_f(product)]-\sum [n\times \Delta G_f(reactant)]

For the given equation:

\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(COCl_2)})]-[(1\times \Delta G^o_f_{(CO_2)})+(1\times \Delta G^o_f_{(CCl_4)})]

Putting values in above equation, we get:

\Delta G^o_{rxn}=[(2\times (-204.9))-((1\times (-394.4))+(1\times (-62.3)))]\\\Delta G^o_{rxn}=46.9kJ=46900J

Conversion factor used = 1 kJ = 1000 J

The expression of K_p for the given reaction:

K_p=\frac{(p_{COCl_2})^2}{p_{CO_2}\times p_{CCl_4}}

We are given:

p_{COCl_2}=0.735atm\\p_{CO_2}=0.140atm\\p_{CCl_4}=0.185atm

Putting values in above equation, we get:

K_p=\frac{(0.735)^2}{0.410\times 0.185}\\\\K_p=20.85

To calculate the gibbs free energy of the reaction, we use the equation:

\Delta G=\Delta G^o+RT\ln K_p

where,

\Delta G = Gibbs' free energy of the reaction = ?

\Delta G^o = Standard gibbs' free energy change of the reaction = 46900 J

R = Gas constant = 8.314J/K mol

T = Temperature = 25^oC=[25+273]K=298K

K_p = equilibrium constant in terms of partial pressure = 20.85

Putting values in above equation, we get:

\Delta G=46900J+(8.314J/K.mol\times 298K\times \ln(20.85))\\\\\Delta G=54425.26J/mol=54.425kJ/mol

Hence, the \Delta G for the reaction is 54.425 kJ/mol

7 0
3 years ago
 How much energy is needed to raise the temperature of 125g of water from 25.0oC to 35.0oC?  The specific heat of water is 4.184
Anvisha [2.4K]

Hello!

To find the amount of energy need to raise the temperature of 125 grams of water from 25.0° C to 35.0° C, we will need to use the formula: q = mcΔt.

In this formula, q is the heat absorbed, m is the mass, c is the specific heat, and Δt is the change in temperature, which is found by final temperature minus the initial temperature.

Firstly, we can find the change in temperature. We are given the initial temperature, which is 25.0° C and the final temperature, which is 35.0° C. It is found by subtract the final temperature from the initial temperature.

35.0° C - 25.0° C = 10.0° C

We are also given the specific heat and the grams of water. With that, we can substitute the given values into the equation and multiply.

q = 125 g × 4.184 J/g °C × 10.0° C

q = 523 J/°C × 10.0° C

q = 5230 J

Therefore, it will take 5230 joules (J) to raise the temperature of the water.

6 0
3 years ago
What is the ph of a 0.15 m solution of ammonium chloride?
Thepotemich [5.8K]
 Best Answer:  <span>(a) 
8.9 x 10^-7 = x^2 / 0.15-x 
x = [OH-] = 0.00037 M 
pOH = 3.4 
pH = 14 - 3.4 = 10.6 

(b) 
Ka = Kw/Kb = 5.6 x 10^-10 = x^2 / 0.20-x 
x = [H+] = 0.000011 M 
pH = 5.0</span>
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D

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3 years ago
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