According of Dalton's law of Partial pressure, the total pressure of a mixture of gases is the sum of the partial pressures of the individual vases in the mixture.
Hence;
The for hydrogen collected over water, we have a mixture of hydrogen gas and water vapour.
Total pressure = pressure of hydrogen gas + vapour pressure of water
Pressure of hydrogen gas = Total pressure - vapour pressure of water
Pressure of hydrogen gas = 636 mmHg - 28.3 mmHg
Pressure of hydrogen gas = 607.7 mmHg
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