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The reaction 2NO(g)+O2(g)−→−2NO2(g) is second order in NO and first order in O2. When [NO]=0.040M, and [O2]=0.035M, the observed

Oksanka [162]

Answer:

(a) The rate of disappearance of $O_{2}$ is: $4.65*10^{-5}$ M/s

(b) The value of rate constant is: 0.83036 $M^{-2}s^{-1}$

(c) The units of rate constant is: $M^{-2}s^{-1}$

(d) The rate will increase by a factor of 3.24

Explanation:

The rate of a reaction can be expressed in terms of the concentrations of the reactants and products in accordance with the balanced equation.

For the given reaction:

$2NO(g)+O_{2}->2NO_{2}$

rate = $-\frac{1}{2} \frac{d}{dt}[NO]$ = $-\frac{d}{dt}[O_{2}]$ = $\frac{1}{2}\frac{d}{dt}[NO_{2}]$ -----(1)

According to the question, the reaction is second order in NO and first order in $O_{2}$ .

Then we can say that, rate = k $[NO]^{2}[O_{2}]$ -----(2)

where k is the rate constant.

The rate of disappearance of NO is given:

$-\frac{d}{dt}[NO]$ = $9.3*10^{-5}$ M/s.

(a) From (1), we can get the rate of disappearance of $O_{2}$ .

Rate of disappearance of $O_{2}$ = $-\frac{d}{dt}[O_{2}]$ = (0.5)*( $9.3*10^{-5}$ ) M/s = $4.65*10^{-5}$ M/s.

(b) The rate of the reaction can be obtained from (1).

rate = $-\frac{1}{2} \frac{d}{dt}[NO]$ = (0.5)*( $9.3*10^{-5}$ )

rate = $4.65*10^{-5}$ M/s

The value of rate constant can be obtained by using (2).

rate constant = k = $\frac{rate}{[NO]^{2}[O_{2}]}$

k = $\frac{4.65*10^{-5}}{(0.040)^{2}(0.035)}$ = 0.83036 $M^{-2}s^{-1}$

(c) The units of the rate constant can be obtained from (2).

k = $\frac{rate}{[NO]^{2}[O_{2}]}$

Substituting the units of rate as M/s and concentrations as M, we get:

$\frac{Ms^{-1} }{M^{3}}$ = $M^{-2}s^{-1}$

(d) The reaction is second order in NO. Rate is proportional to square of the concentration of NO.

$rate\alpha [NO]^{2}$

If the concentration of NO increases by a factor of 1.8, the rate will increase by a factor of $(1.8)^{2}$ = 3.24

5 0

3 years ago

Fe2(SO4)3 +__BaCl2 → __BaSO4 +_<br> FeCl3

Elenna [48]

Answer:

Fe2(SO4)3 + 3BaCl2 → 2FeCl3 + 3BaSO4

8 0

2 years ago

Question 2

Pavel [41]

Tearing paper, Physical Change

6 0

3 years ago

Which of these is a form of a chemical weathering

Illusion [34]

Chemical weathering is caused by rain water reacting with the mineral grains in rocks to form new minerals (clays) and soluble salts. These reactions occur particularly when the water is slightly acidic.

8 0

3 years ago

How many mL are 2.3 mol of CO2 at STP?

kupik [55]

Answer:

0.052mL

Explanation:

1mole of a gas occupy 22.4L.

Therefore, 1 mole of CO2 will also occupy 22.4L.

If 1mole of CO2 occupies 22.4L,

Then 2.3moles of CO2 will occupy = 2.3 x 22.4 = 51.52L

coverting this volume to mL, we simply divide by 1000 as shown below:

51.52/1000 = 0.05152mL = 0.052mL

8 0

3 years ago

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