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kondor19780726 [428]
2 years ago
8

CO(g)+2H2(g)⇌CH3OH(g)CO(g)+2H2(g)⇌CH3OH(g) This reaction is carried out at a different temperature with initial concentrations o

f [CO]=0.27M[CO]=0.27M and [H2]=0.49M[H2]=0.49M. At equilibrium, the concentration of CH3OHCH3OH is 0.11 MM. Find the equilibrium constant at this temperature.
Chemistry
1 answer:
Katarina [22]2 years ago
8 0

Answer:

9.4

Explanation:

The equation for the reaction can be represented as:

CO_{(g)}    +      2H_2O_{(g)}   ⇄  CH_3OH_{(g)}

The ICE table can be represented as:

                                  CO_{(g)}    +      2H_2_{(g)}   ⇄  CH_3OH_{(g)}

Initial                          0.27             0.49              0.0

Change                      -x                  -2x                 x

Equilibrium               0.27 - x         0.49 -2x          x

We can now say that the concentration of  CH_3OH_{(g)} at equilibrium is x;

Let's not forget that at equilibrium  CH_3OH_{(g)} = 0.11 M

So:

x =  [CH_3OH_{(g)}] = 0.11 M

[CO_{(g)}] = 0.27 - x

[CO_{(g)}] = 0.27 - 0.11

[CO_{(g)}] = 0.16 M

[2H_2_{(g)}] = (0.49 - 2x)

[2H_2_{(g)}] = (0.49 - 2(0.11))

[2H_2_{(g)}] = 0.49 - 0.22

[2H_2_{(g)}] = 0.27 M

K_C = \frac{[CH_3OH]}{[CO][H_2]^2}

K_C = \frac{(0.11)}{(0.16)[(0.27)^2}

K_C = 9.4307

K_C = 9.4

∴ The equilibrium constant at that temperature = 9.4

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The protein lysozyme unfolds at a transition temperature of 75.5°C, and the standard enthalpy of transition is 509 kJ mol-1. Cal
spin [16.1K]

Answer:

0.4774 KJ/K.mol

Explanation:

We are told that the transition at 25.0°C occurs in three steps. Steps i, ii and iii.

Thus;

the entropy of unfolding of lysozyme = ΔS_i + ΔS_ii + ΔS_iii

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Now, for the first process, ΔS_i is given as;

ΔS_i = C_p,m × In(T2/T1)

We are given;

T1 = 25°C = 25 + 273.15K = 298.15 K

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Thus;

ΔS_i = C_p,m × In(348.65/298.15)

Now, for the third process, ΔS_iii is given as;

ΔS_iii = (C_p,m + 6.28 kJ/K.mol) × In(T1/T2)

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ΔS_iii = (C_p,m + 6.28 kJ/K.mol) × In(298.15/348.65)

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In(298.15/348.65) can also be written as;

In(348.65/298.15)^(-1) or

- In(348.65/298.15)

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ΔS_iii = - [(C_p,m + 6.28 kJ/K.mol) × In(298.15/348.65)]

Now, let's add ΔS_iii to ΔS_i to get;

ΔS_i + ΔS_iii = [C_p,m × In(348.65/298.15)] + [(-C_p,m - 6.28 kJ/K.mol) × In(348.65/298.15)]

ΔS_i + ΔS_iii = [C_p,m × In(348.65/298.15)] - [C_p,m × In(348.65/298.15)] - [6.28In(348.65/298.15)]

First 2 terms will cancel out to give;

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Thus;

ΔS_ii = (509 KJ/K.mol)/348.65

ΔS_ii = 1.46 KJ/K.mol

Thus;

the entropy of unfolding of lysozyme = ΔS_i + ΔS_ii + ΔS_iii = -0.9826 + 1.46 = 0.4774 KJ/K.mol

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