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kondor19780726 [428]
3 years ago
8

CO(g)+2H2(g)⇌CH3OH(g)CO(g)+2H2(g)⇌CH3OH(g) This reaction is carried out at a different temperature with initial concentrations o

f [CO]=0.27M[CO]=0.27M and [H2]=0.49M[H2]=0.49M. At equilibrium, the concentration of CH3OHCH3OH is 0.11 MM. Find the equilibrium constant at this temperature.
Chemistry
1 answer:
Katarina [22]3 years ago
8 0

Answer:

9.4

Explanation:

The equation for the reaction can be represented as:

CO_{(g)}    +      2H_2O_{(g)}   ⇄  CH_3OH_{(g)}

The ICE table can be represented as:

                                  CO_{(g)}    +      2H_2_{(g)}   ⇄  CH_3OH_{(g)}

Initial                          0.27             0.49              0.0

Change                      -x                  -2x                 x

Equilibrium               0.27 - x         0.49 -2x          x

We can now say that the concentration of  CH_3OH_{(g)} at equilibrium is x;

Let's not forget that at equilibrium  CH_3OH_{(g)} = 0.11 M

So:

x =  [CH_3OH_{(g)}] = 0.11 M

[CO_{(g)}] = 0.27 - x

[CO_{(g)}] = 0.27 - 0.11

[CO_{(g)}] = 0.16 M

[2H_2_{(g)}] = (0.49 - 2x)

[2H_2_{(g)}] = (0.49 - 2(0.11))

[2H_2_{(g)}] = 0.49 - 0.22

[2H_2_{(g)}] = 0.27 M

K_C = \frac{[CH_3OH]}{[CO][H_2]^2}

K_C = \frac{(0.11)}{(0.16)[(0.27)^2}

K_C = 9.4307

K_C = 9.4

∴ The equilibrium constant at that temperature = 9.4

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Explanation:

Hello,

In this case, the mass balance for each substance is given by:

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NOTE: notice the result is independent of the value of the assumed feed, it means that no matter the basis, the compositions will be the same for the same recovery of butane at the feed, only the flows will change.

Regards.

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