Answer:
time taken for one-half of the BrO⁻ ion to react is t= 27.45 secs
Explanation:
equation of reaction
3BrO⁻(aq) → BrO₃⁻(aq) + 2Br⁻(aq) (second order reaction)
given
the slope of the graph is 0.056M⁻¹s⁻¹ = k(constant)
initial concentration [A]₀ = 0.65M
for second order reaction,we can calculate the time taken for one-half of the BrO- ion to react using:
=
₀ ⁺ k × t
where initial concentration [A]₀ = 0.65M
[A] = [A]₀÷2 = 0.325M
=
+ 0.056M⁻¹s⁻¹ × t
3.077= 1.54 + 0.056t
3.077-1.54=0.056t
1.537=0.056t
t= 27.45 secs
Solution :
Given :
Amount of anserine solution = 0.200 M
pH value is = 7.20
Preparation of 0.04 M solution of anserine from the 0.2 M solution.
0.2 M x = 0.04 M x 1000 ml
= 200 ml
So the 200 ml of 0.2 M anserine solution is required to prepare0.04 M of anserine.
0.1 M x = 0.04 x 1000 ml
= 400 ml
Therefore, 400 ml of HCl is needed.