The trick here is to realize the 4 applies only to the hydrogen. The 3 applies only to the oxygen.
There are 2 nitrogens in the formula. So if the entire molecule represents 0.286 mols. The individual mols of each part of the formula is just multiplied by the number of moles of the molecule. In formula form
Number of moles of the atoms making up the molecule = number of atoms from the formula * mols of the molecule.
For many solids dissolved in liquid water, the solubility increases with temperature.
The increase in kinetic energy that comes with higher temperatures allows the solvent molecules to more effectively break apart the solute molecules that are held together by intermolecular attractions.