What is pH of a solution where [H+]=0.000044 M

Chemistry

1 answer:

enot [183]2 years ago

8 0

Answer:

pH = 4.36

Explanation:

From definition of potenz hydrogen,

pH = -log[H+]

pH = -log(0.000044)

pH = 4.36

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If 8.50 g of phosphorus reacts with hydrogen gas at 2.00 atm in a 10.0-L container at 298 K, calculate the moles of PH3 produced

ahrayia [7]

Answer:

The moles of PH₃ produced are 0.2742 and the total number of moles of gas present at the end of the reaction is 0.6809.

Explanation:

Phosphorus reacts with H₂ according to the balanced equation:

P₄ (s) + 6 H₂ (g) ⇒ 4 PH₃ (g)

By stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of each compound participate in the reaction:

P₄: 1 mole
H₂: 6 moles
PH₃:4 moles

Being the molar mass of the compounds:

P₄: 124 g/mole
H₂: 2 g/mole
PH₃: 34 g/mole

The following mass amounts of each compound participate in the reaction:

P₄: 1 mole* 124 g/mole= 124 g
H₂: 6 mole* 2 g/mole= 12 g
PH₃: 4 moles* 34 g/mole= 136 g

An ideal gas is characterized by three state variables: absolute pressure (P), volume (V), and absolute temperature (T). The relationship between them constitutes the ideal gas law, an equation that relates the three variables if the amount of substance, number of moles n, remains constant and where R is the molar constant of the gases:

P * V = n * R * T

In this case you know:

P= 2 atm
V= 10 L
n= ?
R= 0.082 $\frac{atm*L}{mol*K}$
T= 298 K

Replacing:

2 atm*10 L= n*0.082 $\frac{atm*L}{mol*K}$ *298 K

and solving you get:

$n=\frac{2 atm*10 L}{0.082\frac{atm*L}{mol*K}*298 K }$

n=0.818 moles

The limiting reagent is one that is consumed first in its entirety, determining the amount of product in the reaction. When the limiting reagent is finished, the chemical reaction will stop.

To determine the limiting reagent, you can use a simple rule of three as follows: if 6 moles of H₂ react with 124 g of P₄, 0.818 moles of H₂ with how much mass of P₄ will it react?

$mass of P_{4}=\frac{0.818 moles of H_{2}*124 grams of P_{4}}{6 moles of H_{2}}$

mass of P₄= 16.90 grams

But 16.90 grams of P₄ are not available, 8.50 grams are available. Since you have less mass than you need to react with 0.818 moles of H₂, phosphorus P₄ will be the limiting reagent.

Then you can apply the following rules of three: