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zvonat [6]
3 years ago
13

At T = 250 °C the reaction PCl5(g) PCl3(g) + Cl2(g) has an equilibrium constant in terms of pressures Kp = 2.15. (a) Suppose the

initial partial pressure of PCl5 is 0.548 atm, and PPCl3 = PCl2 = 0.780 atm. Calculate the reaction quotient Qp and state whether the reaction proceeds to the right or to the left as equilibrium is approached
Chemistry
1 answer:
Ganezh [65]3 years ago
7 0

Answer:

To the right

Explanation:

Step 1: Given data

  • Partial pressure of PCl₅ (pPCl₅) = 0.548 atm
  • Partial pressure of PCl₃ (pCl₃) = 0.780 atm
  • Partial pressure of Cl₂ (pCl₂) = 0.780 atm

Step 2: Write the balanced equation

PCl₅(g) ⇄ PCl₃(g) + Cl₂(g)

Step 3: Calculate the pressure reaction quotient

Q_p = \frac{pPCl_3 \times pCl_2 }{pPCl_5} = \frac{0.780 \times 0.780 }{0.548} =1.11

Step 4: Determine whether the reaction proceeds to the right or to the left as equilibrium is approached

Since <em>Qp < Kp</em>, the reaction will proceed to the right to attain the equilibrium.

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Arterial blood contains about 0.25 g of oxygen per liter at 37°C and standard atmospheric pressure. Under these conditions, the
Olin [163]

Firstly we need to determine the partial pressure of O2:

\begin{gathered} P_{O_2}=X\times P_T \\ P_{O_2}:partial\text{ }pressure \\ X:mole\text{ }fraction \\ P_T:total\text{ }pressure \\  \\ P_{O_2}=0.209\times0.35\text{ }atm \\ P_{O_2}=0.073\text{ }atm \end{gathered}

We will now use the Henry's Law equation to determine the solubility of the gas:

\begin{gathered} c=K_H\times P_{O_2} \\ c:solubility\text{ }or\text{ }concentration\text{ }of\text{ }the\text{ }gas(M) \\ K_H:Henry^{\prime}sLawconstant=3.7\times10^{-2}M\text{ }atm^{-1} \\ P_{O_2}:partial\text{ }pressure\text{ }of\text{ }the\text{ }gas=0.073atm \\  \\ c=3.7\times10^{-2}M\text{ }atm^{-1}\times0.073 \\ c=2.7\times10^{-3}M \end{gathered}

Answer: Solubility is 2.7x10^-3 M

6 0
1 year ago
Which of the following statements about the combustion of glucose with oxygen to form water and carbon dioxide (C6H12O6 + 6 O2 →
worty [1.4K]

Answer:

The correct statement is:

E - The entropy of the products is greater than the entropy of the reactants.

Explanation:

C₆H₁₂O₆ + 6 O₂ → 6 CO₂ + 6 H₂O

As glucose is a large molecule and then it is transformed into many molecules of water and carbon dioxide, the entropy of the system increases. If the number of molecules increases, the disorder increases.

Initial state: 7 molecules (1 glucose + 6 oxygen)

Final state: 12 molecules (6 carbon dioxide + 6 water)

3 0
3 years ago
Read 2 more answers
For a certain experiment, a student requires 100 milliliters of a solution that is 8% HCl (hydrochloric acid). The storeroom has
exis [7]

Answer:

70 mL of 5% HCl and 30 mL of 15% HCl

Explanation:

We will designate x to be the fraction of the final solution that is composed of 5% HCl, and y to be the fraction of the final solution that is composed of 15% HCl. Since the percentage of the final solution is 8%, we can write the following expression:

5x + 15y = 8

Since x and y are fractions of a total, they must equal one:

x + y = 1

This is a system of two equations with two unknowns. We will proceed to solve for x. First, an expression for y is found:

y = 1 - x

This expression is substituted into the first equation and we solve for x.

5x + 15(1 - x) = 8

5x+ 15 - 15x = 8

-10x = -7

x = 7/10 = 0.7

We then calculate the value of y:

y = 1 - x = 1 - 0.7 = 0.3

Thus 0.7 of the 100 mL will be the 5% HCl solution, so the volume of 5% HCl we need is:

(100 mL)(0.7) = 70 mL

Similarly, the volume of 15% HCl we need is:

(100 mL)(0.3) = 30 mL

3 0
3 years ago
The volume of a sample of oxygen is 300.0 mL, when the pressure is 1.00 atm and the temperature is 300K. At what pressure will t
Brut [27]

Answer:

The new pressure is 0.5 atm

Explanation:

Step 1: Data given

Volume of oxygen = 300 mL = 0.300 L

Pressure = 1.00 atm

Temperature = 300 K

The volume increases to 1000mL = 1.00 L

The temperature increases to 500 K

Step 2: Calculate the new pressure

(P1*V1)/T1 = (P2*V2)/T2

⇒with P1 = the initial pressure = 1.00 atm

⇒with V1 = the initial volume = 0.300 L

⇒with T1 = the initial temperature = 300 K

⇒with P2 = the new pressure = TO BE DETERMINED

⇒with V2 = the increased volume = 1.00 L

⇒with T2 = the increased temperature = 500 K

(1.00 atm* 0.300 L)/300 K = (P2 * 1.00L) / 500 K

P2 = (1.00 *0.300 * 500) / (300 *1.00)

P2 = 0.5 atm

The new pressure is 0.5 atm

4 0
3 years ago
An impurity sometimes found in Ca₃(PO₄)₂ is Fe₂O₃, which is removed during the production of phosphorus as ferrophosphorus (Fe₂P
Citrus2011 [14]

This impurity is troubling from an economic standpoint because it lead to decrease in the yield of phosphorus

  • Ferrophosphorus is a byproduct of phosphorus production in submerged-arc furnaces , by their reduction with carbon. It is formed from the iron oxide impurities.
  • Iron impurities present in the calcium phosphate will be precipitated out as the iron phosphate which eventually will lead to the decrease in the yield of phosphorous during the production of phosphorous.

Thus we can conclude that Fe₂P causes decrease in yield

Learn more about production of phosphorus at brainly.com/question/13337198

#SPJ4

6 0
2 years ago
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