Answer:
See explanation and image attached
Explanation:
The reaction of 1-bromo-2-tert-butylcyclohexane with potassium tert-butoxide is an elimination reaction that occurs by E2 mechanism.
The E2 reaction proceeds faster when the hydrogens are in an antiperiplanar position at an angle of 180 degrees.
This is only attainable in the trans isomer of 1-bromo-2-tert-butylcyclohexane. Hence trans 1-bromo-2-tert-butylcyclohexane reacts faster with potassium tert-butoxide
Answer: The osmotic pressure of a solution is 53.05 atm
Explanation:
To calculate the concentration of solute, we use the equation for osmotic pressure, which is:
Or,
where,
= osmotic pressure of the solution = ?
i = Van't hoff factor = 1 (for non-electrolytes)
Mass of solute (methanol) = 22.3 g
Volume of solution = 321 mL
R = Gas constant =
T = temperature of the solution =
Putting values in above equation, we get:
Hence, the osmotic pressure of a solution is 53.05 atm