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Valentin [98]
3 years ago
14

Warming a gas at constant volume and a pressure of 1.50 atm from 27 degrees Celsius to 127 degrees Celsius gives a final pressur

e of
Chemistry
1 answer:
tankabanditka [31]3 years ago
8 0

Answer:

Final pressure of gas = 2 atm

Explanation:

Given data:

Initial pressure of gas = 1.50 atm

Initial temperature = 27°C

Final temperature = 127°C

Final pressure of gas = ?

Solution:

Initial temperature = 27°C (27+273 = 300 K)

Final temperature = 127°C ( 127+273 = 400 K)

According to Gay-Lussac Law,

The pressure of given amount of a gas is directly proportional to its temperature at constant volume and number of moles.

Mathematical relationship:

P₁/T₁ = P₂/T₂

Now we will put the values in formula:

1.50  atm / 300 K = P₂/400 K

P₂ = 1.50 atm × 400 K / 300 K

P₂ = 600 atm. K /300 K

P₂ = 2 atm

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An exacuted glass vessel weighs 50 g when empty, 148g when filled with an liquid of density o.989/cc and 50.5 g whenfilled with
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MW of gas : 124.12 g/mol

<h3>Further explanation  </h3>

Density is a quantity derived from the mass and volume  

Density is the ratio of mass per unit volume  

With the same mass, the volume of objects that have a high density will be smaller than objects with a smaller type of density  

The unit of density can be expressed in g/cm³ or kg/m³  

Density formula:  

\large {\boxed {\bold {\rho ~ = ~ \frac {m} {V}}}}

ρ = density  

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glass vessel wieight = 50 g

glass vessel + liquid = 148 ⇒ liquid = 148 - 50 =98 g

volume of glass vessel :

\tt V=\dfrac{m}{\rho}=\dfrac{98}{0.989}=99.1~ml

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m = 50.5 - 50 = 0.5 g

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T = 300 K

\tt PV=\dfrac{mass(m)}{MW}.RT\\\\MW=\dfrac{m.RT}{PV}\\\\Mw=\dfrac{0.5\times 0.082\times 300}{1\times 0.0991}=124.12~g/mol

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Calculate the solubility of hydrogen in water at an atmospheric pressure of 0.380 atm (a typical value at high altitude).
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The question is incomplete, here is the complete question:

Calculate the solubility of hydrogen in water at an atmospheric pressure of 0.380 atm (a typical value at high altitude).

Atmospheric Gas         Mole Fraction      kH mol/(L*atm)

           N_2                         7.81\times 10^{-1}         6.70\times 10^{-4}

           O_2                         2.10\times 10^{-1}        1.30\times 10^{-3}

           Ar                          9.34\times 10^{-3}        1.40\times 10^{-3}

          CO_2                        3.33\times 10^{-4}        3.50\times 10^{-2}

          CH_4                       2.00\times 10^{-6}         1.40\times 10^{-3}

          H_2                          5.00\times 10^{-7}         7.80\times 10^{-4}

<u>Answer:</u> The solubility of hydrogen gas in water at given atmospheric pressure is 1.48\times 10^{-10}M

<u>Explanation:</u>

To calculate the partial pressure of hydrogen gas, we use the equation given by Raoult's law, which is:

p_{\text{hydrogen gas}}=p_T\times \chi_{\text{hydrogen gas}}

where,

p_A = partial pressure of hydrogen gas = ?

p_T = total pressure = 0.380 atm

\chi_A = mole fraction of hydrogen gas = 5.00\times 10^{-7}

Putting values in above equation, we get:

p_{\text{hydrogen gas}}=0.380\times 5.00\times 10^{-7}\\\\p_{\text{hydrogen gas}}=1.9\times 10^{-7}atm

To calculate the molar solubility, we use the equation given by Henry's law, which is:

C_{H_2}=K_H\times p_{H_2}

where,

K_H = Henry's constant = 7.80\times 10^{-4}mol/L.atm

p_{H_2} = partial pressure of hydrogen gas = 1.9\times 10^{-7}atm

Putting values in above equation, we get:

C_{H_2}=7.80\times 10^{-4}mol/L.atm\times 1.9\times 10^{-7}atm\\\\C_{CO_2}=1.48\times 10^{-10}M

Hence, the solubility of hydrogen gas in water at given atmospheric pressure is 1.48\times 10^{-10}M

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