Answer:
9.36
Explanation:
Sodium formate is the conjugate base of formic acid.
Also,
for sodium formate is 
Given that:
of formic acid = 
And, 
So,
Concentration = 0.35 M
HCOONa ⇒ Na⁺ + HCOO⁻
Consider the ICE take for the formate ion as:
HCOO⁻ + H₂O ⇄ HCOOH + OH⁻
At t=0 0.35 - -
At t =equilibrium (0.35-x) x x
The expression for dissociation constant of sodium formate is:
![K_{b}=\frac {[OH^-][HCOOH]}{[HCOO^-]}](https://tex.z-dn.net/?f=K_%7Bb%7D%3D%5Cfrac%20%7B%5BOH%5E-%5D%5BHCOOH%5D%7D%7B%5BHCOO%5E-%5D%7D)
Solving for x, we get:
x = 0.44×10⁻⁵ M
pOH = -log[OH⁻] = -log(0.44×10⁻⁵) = 4.64
pH + pOH = 14
So,
<u>pH = 14 - 4.64 = 9.36</u>
In order to <span>decrease the pressure of a gas inside a closed cubical container, you need to decrease the temperature of the container. The volume of the system is rigid so it means volume is constant. By the ideal gas law, temperature and pressure are directly related. Increasing the temperature, increases the pressure and the opposite to happens.</span>
This question is describing the following chemical reaction at equilibrium:
And provides the relative amounts of both A and B at 25 °C and 75 °C, this means the equilibrium expressions and equilibrium constants can be written as:
Thus, by recalling the Van't Hoff's equation, we can write:
Hence, we solve for the enthalpy change as follows:
Finally, we plug in the numbers to obtain:
![\Delta H=\frac{-8.314\frac{J}{mol*K} *ln(0.25/9)}{[\frac{1}{(75+273.15)K} -\frac{1}{(25+273.15)K} ] } \\\\\\\Delta H=4,785.1\frac{J}{mol}](https://tex.z-dn.net/?f=%5CDelta%20H%3D%5Cfrac%7B-8.314%5Cfrac%7BJ%7D%7Bmol%2AK%7D%20%2Aln%280.25%2F9%29%7D%7B%5B%5Cfrac%7B1%7D%7B%2875%2B273.15%29K%7D%20-%5Cfrac%7B1%7D%7B%2825%2B273.15%29K%7D%20%5D%20%7D%20%5C%5C%5C%5C%5C%5C%5CDelta%20H%3D4%2C785.1%5Cfrac%7BJ%7D%7Bmol%7D)
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