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Effectus [21]
4 years ago
13

A weak base is titrated with a hydrochloric acid solution. What is the pH at the equivalence point?A) equal to pKaB) equal to 7C

) equal to pKbD) greater than 7E) less than 7
Chemistry
1 answer:
zvonat [6]4 years ago
4 0

Answer:

E) less than 7

Explanation:

pH is defined as the negative logarithm of the concentration of hydrogen ions.

Thus,  

pH = - log [H⁺]

pH scale generally runs from 1 to 14 where pH = 7 represents neutral medium, pH < 7 represents acidic medium and pH > 7 represents basic medium.

Strong acids dissociate completely and when they react with base they form a salt of weak base and strong acid.

For example, BOH is a weak base and HCl is the hydrochloric acid.

So,

BOH+HCl\rightarrow BCl+H_2O

<u>Thus, the salt is of weak base and strong acid which corresponds to pH less than 7.</u>

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The question is incomplete, here is the complete question:

The rate constant of a certain reaction is known to obey the Arrhenius equation, and to have an activation energy Ea = 71.0 kJ/mol . If the rate constant of this reaction is 6.7 M^(-1)*s^(-1) at 244.0 degrees Celsius, what will the rate constant be at 324.0 degrees Celsius?

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To calculate rate constant at two different temperatures of the reaction, we use Arrhenius equation, which is:

\ln(\frac{K_{324^oC}}{K_{244^oC}})=\frac{E_a}{R}[\frac{1}{T_1}-\frac{1}{T_2}]

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K_{244^oC} = equilibrium constant at 244°C = 6.7M^{-1}s^{-1}

K_{324^oC} = equilibrium constant at 324°C = ?

E_a = Activation energy = 71.0 kJ/mol = 71000 J/mol   (Conversion factor:  1 kJ = 1000 J)

R = Gas constant = 8.314 J/mol K

T_1 = initial temperature = 244^oC=[273+244]K=517K

T_2 = final temperature = 324^oC=[273+324]K=597K

Putting values in above equation, we get:

\ln(\frac{K_{324^oC}}{6.7})=\frac{71000J}{8.314J/mol.K}[\frac{1}{517}-\frac{1}{597}]\\\\K_{324^oC}=61.29M^{-1}s^{-1}

Hence, the rate constant at 324°C is 61.29M^{-1}s^{-1}

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