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3 years ago

What is the reactivity trend of halogens?

1 answer:

3 0

Reactivity trends of halogen:

1) Melting point and boiling points increased down the
group

2) Colour becomes darker.
E.g. Fluorine (pale yellow)
Chlorine (yellowish-green)
Bromine (reddish-brown)
Iodine (purplish-black)
Astatine (black)

3) The reactivity decreases down the group.
Reactivity:
F > Cl > Br > I > At

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What is the volume of a gas if 0.182 moles of the gas is at 1.99 atm and 83.4oC?

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1 year ago

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3 years ago

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From these two reactions at 298 K, V2O3(s) + 3CO(g) → 2V(s) + 3CO2(g); ΔH° = 369.8 kJ; ΔS° = 8.3 J/K V2O5(s) + 2CO(g) → V2O3(s)

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Answer:

ΔG° = -133,1 kJ

Explanation:

For the reactions:

(1) V₂O₃(s) + 3CO(g) → 2V(s) + 3CO₂(g); ΔH° = 369,8 kJ; ΔS° = 8,3 J/K

(2) V₂O₅(s) + 2CO(g) → V₂O₃(s) + 2CO₂(g); ΔH° = –234,2 kJ; ΔS° = 0,2 J/K

By Hess's law it is possible to obtain the ΔH° and ΔS° of:

2V(s) + 5CO₂(g) → V₂O₅(s) + 5CO(g)

Substracting -(1)-(2), that means:

ΔH° = -369,8 kJ - (-234,2 kJ) = -135,6 kJ

ΔS° = - 8,3 J/K - 0,2 J/K = -8,5 J/K

Using: ΔG° = ΔH° - TΔS° at 298K

ΔG° = -135,6 kJ - 298K×-8,5x10⁻³kJ/K

ΔG° = -133,1 kJ

I hope it helps!

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