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3 years ago

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In a particular electroplating process, the metal being plated has a +4 charge. If 861.8 C of charge pass through the cell, how

many moles of metal should be plated? Useful information: F = 96,500 C/mol e- Provide your response to four digits after the decimal.

1 answer:

Xelga [282]3 years ago

3 0

Answer: $2.2326\times 10^{-3}$ moles

Explanation:

We are given:

Moles of electron = 1 mole

According to mole concept:

1 mole of an atom contains $6.022\times 10^{23}$ number of particles.

We know that:

Charge on 1 electron = $1.6\times 10^{-19}C$

Charge on 1 mole of electrons = $1.6\times 10^{-19}\times 6.022\times 10^{23}=96500C$

The metal being plated has a +4 charge, thus the equation will be:

$M^{4+}+4e^-\rightarrow M$

$4\times 96500C$ of electricity deposits = 1 mole of metal

Thus 861.8 C of electricity deposits = $\frac{1}{4\times 96500}\times 861.8=2.2326\times 10^{-3}$ moles of metal

Thus $2.2326\times 10^{-3}$ moles of metal should be plated

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How many milliliters of .085 m naoh are required to titrate 25 ml of .072 m hbr to the equivalence point?

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Excess magnesium reacts with 165.0 grams of hydrochloric acid in a single displacement reaction.

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Answer:

The volume of hydrogen gas produced will be approximately 50.7 liters under STP.

Explanation:

Relative atomic mass data from a modern periodic table:

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Cl: 35.45.

Magnesium is a reactive metal. It reacts with hydrochloric acid to produce

Hydrogen gas $\rm H_2$ , and
Magnesium chloride, which is a salt.

The chemical equation will be something like

$\rm ?\;Mg\;(s) + ?\;HCl \;(aq)\to ?\;H_2 \;(g)+ [\text{Formula of the Salt}]$ ,

where the coefficients and the formula of the salt are to be found.

To determine the number of moles of $\rm H_2$ that will be produced, first find the formula of the salt, magnesium chloride.

Magnesium is a group 2 metal. The oxidation state of magnesium in compounds tends to be +2.

On the other hand, the charge on each chloride ion is -1. Each magnesium ion needs to pair up with two chloride ions for the charge to balance in the salt, magnesium chloride. The formula for the salt will be $\rm MgCl_2$ .

$\rm ?\;Mg\;(s) + ?\;HCl\;(aq) \to ?\;H_2 \;(g)+ ?\;MgCl_2\;(aq)$ .

Balance the equation. $\rm MgCl_2$ contains the largest number of atoms among all species in this reaction. Start by setting its coefficient to 1.

$\rm ?\;Mg\;(s) + ?\;HCl\;(aq) \to ?\;H_2 \;(g)+ {\bf 1\;MgCl_2}\;(aq)$ .

The number of $\rm Mg$ and $\rm Cl$ atoms shall be the same on both sides. Therefore

$\rm {\bf 1\;Mg}\;(s) + {\bf 2\;HCl}\;(aq) \to ?\;H_2 \;(g)+ {1\;\underset{\wedge}{Mg}\underset{\wedge}{Cl_2}}\;(aq)$ .

The number of $\rm H$ atoms shall also conserve. Hence the equation:

$\rm {1\;Mg}\;(s) + {2\;\underset{\wedge}{H}Cl}\;(aq) \to {\bf 1\;H_2 \;(g)}+ {1\;MgCl_2}\;(aq)$ .

How many moles of HCl are available?

$M(\rm HCl) = 1.008 + 35.45 = 36.458\;g\cdot mol^{-1}$ .

$\displaystyle n({\rm HCl}) = \frac{m(\text{HCl})}{M(\text{HCl})} = \rm \frac{165.0\;g}{36.458\;g\cdot mol^{-1}} = 4.52576\;mol$ .

How many moles of Hydrogen gas will be produced?

Refer to the balanced chemical equation, the coefficient in front of $\rm HCl$ is 2 while the coefficient in front of $\rm H_2$ is 1. In other words, it will take two moles of $\rm HCl$ to produce one mole of $\rm H_2$ . $\rm 4.52576\;mol$ of $\rm HCl$ will produce only one half as much $\rm H_2$ .

Alternatively, consider the ratio between the coefficient in front of $\rm H_2$ and $\rm HCl$ is:

$\displaystyle \frac{n(\text{H}_2)}{n(\text{HCl})} = \frac{1}{2}$ .

$\displaystyle n(\text{H}_2) = n(\text{HCl})\cdot \frac{n(\text{H}_2)}{n(\text{HCl})} = \frac{1}{2}\;n(\text{HCl}) = \rm \frac{1}{2}\times 4.52576\;mol = 2.26288\;mol$ .

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$V(\text{H}_2) = \rm 2.26288\;mol\times 22.7\;L\cdot mol^{-1} = 51.37\; L$ .

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