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Travka [436]
3 years ago
14

In a particular electroplating process, the metal being plated has a +4 charge. If 861.8 C of charge pass through the cell, how

many moles of metal should be plated? Useful information: F = 96,500 C/mol e- Provide your response to four digits after the decimal.
Chemistry
1 answer:
Xelga [282]3 years ago
3 0

Answer: 2.2326\times 10^{-3} moles

Explanation:

We are given:

Moles of electron = 1 mole

According to mole concept:

1 mole of an atom contains 6.022\times 10^{23} number of particles.

We know that:

Charge on 1 electron = 1.6\times 10^{-19}C

Charge on 1 mole of electrons = 1.6\times 10^{-19}\times 6.022\times 10^{23}=96500C

The metal being plated has a +4 charge, thus the equation will be:

M^{4+}+4e^-\rightarrow M

4\times 96500C of electricity deposits = 1 mole of metal

Thus 861.8 C of electricity deposits =\frac{1}{4\times 96500}\times 861.8=2.2326\times 10^{-3} moles of metal

Thus 2.2326\times 10^{-3} moles of metal should be plated

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What volume of oxygen (in L) is produced
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Answer:

12.36 L.

Explanation:

We'll begin by calculating the number of mole in 147.1 g of lead(II) nitrate, Pb(NO₃)₂. This can be obtained as follow:

Molar mass of Pb(NO₃)₂ = 207.2 + 2[14.01 + (16×3)]

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Mole of Pb(NO₃)₂ =?

Mole = mass / Molar mass

Mole of Pb(NO₃)₂ = 147.1 / 331.22

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Next, we shall determine the number of mole of oxygen gas, O₂, produce from the reaction. This can be obtained as follow:

2Pb(NO₃)₂ —> 2PbO + 4NO₂ + O₂

From the balanced equation above,

2 moles of Pb(NO₃)₂ decomposed to produce 1 mole of O₂.

Therefore, 1.104 moles of Pb(NO₃)₂ will decompose to produce = (1.104 × 1)/2 = 0.552 mole of O₂.

Finally, we shall determine the volume occupied by 0.552 mole of oxygen gas, O₂. This can be obtained as follow:

1 mole of O₂ occupied 22.4 L at STP.

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What would be the major product if 1,4-dibromo-4-methylpentane was allowed to react with:
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Answer : The correct answer for a) 4-bromo-2-iodo-4-methyl pentane and b)5-bromo-2-ethoxy-2-methyl pentane.

A) Reaction with NaI :

Reaction of alkyl halide with NaI is known as Finkelstein Reaction . The acetone is used as solvent . It involves bimolecular nucleophillic substitution rmechanism (SN²) . There is replecement of one halogen with other occurs .

The incoming Nucleophile(Nu⁻) (halide) attacks on carbon from back side , while the leaving group (halide) leaves the compound from front side , simultaneously. The product so formed have is inverted .(Image)

NaI releases I⁻ ion which act as nucelophile and attacks on C1 carbon and Br⁻ from C1 carbon is released . Out of two bromines at C1 and C4 carbons , C1 is primary carbon which is less sterically hindered while C-4 is tertiary carbon and sterically hindered . So it is easy for incoming Nu⁻ to attack on C1 carbon .So Br⁻ is repleaced by I⁻.

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The product formed as a result is 5-bromo-2-ethoxy-2-methyl pentane.

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