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emmainna [20.7K]
3 years ago
14

Which of the following best describes the difference in bonding between two hydrogen atoms and two carbon atoms?

Chemistry
1 answer:
valentinak56 [21]3 years ago
4 0

Answer :

2. Hydrogen forms bonds through the overlap of 1s atomic orbitals and the sharing of electrons between atoms. Carbon forms bonds through the overlapping of sp hybrid atomic orbitals and the sharing of electrons between carbon atoms.

Explanation:

The H-H bond is formed by the overlap of two 1s orbitals and the sharing of electrons between the two atoms.

A carbon atom must use the overlap of hybridized atomic orbitals and the sharing of electrons to bond with another carbon atoms.

1. is <em>wrong</em> because H can use only its <em>1s orbital</em> for bonding.

3. is <em>wrong</em> because C must <em>share electrons</em> to form a carbon-carbon bond.

4. is <em>wrong</em> because <em>C does NOT use overlapping of 2s orbitals</em> for bonding. It uses the overlap of hybridized orbitals.

5. is <em>wrong</em> because H must <em>share electrons</em> to form an H-H bond.

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The equilibrium constant Kc for the reaction PCl3(g) + Cl2(g) ⇌ PCl5(g) is 49 at 230°C. If 0.70 mol of PCl3 is added to 0.70 mol
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Answer : The correct option is, (B) 0.11 M

Solution :

First we have to calculate the concentration PCl_3 and Cl_2.

\text{Concentration of }PCl_3=\frac{\text{Moles of }PCl_3}{\text{Volume of solution}}

\text{Concentration of }PCl_3=\frac{0.70moles}{1.0L}=0.70M

\text{Concentration of }Cl_2=\frac{\text{Moles of }Cl_2}{\text{Volume of solution}}

\text{Concentration of }Cl_2=\frac{0.70moles}{1.0L}=0.70M

The given equilibrium reaction is,

                            PCl_3(g)+Cl_2(g)\rightleftharpoons PCl_5(g)

Initially                 0.70        0.70              0

At equilibrium    (0.70-x)   (0.70-x)           x

The expression of K_c will be,

K_c=\frac{[PCl_5]}{[PCl_3][Cl_2]}

K_c=\frac{(x)}{(0.70-x)\times (0.70-x)}

Now put all the given values in the above expression, we get:

49=\frac{(x)}{(0.70-x)\times (0.70-x)}

By solving the term x, we get

x=0.59\text{ and }0.83

From the values of 'x' we conclude that, x = 0.83 can not more than initial concentration. So, the value of 'x' which is equal to 0.83 is not consider.

Thus, the concentration of PCl_3 at equilibrium = (0.70-x) = (0.70-0.59) = 0.11 M

The concentration of Cl_2 at equilibrium = (0.70-x) = (0.70-0.59) = 0.11 M

The concentration of PCl_5 at equilibrium = x = 0.59 M

Therefore, the concentration of PCl_3 at equilibrium is 0.11 M

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