Answer: The half-life of a first-order reaction is, 
Explanation:
All the radioactive reactions follows first order kinetics.
Rate law expression for first order kinetics is given by the equation:
![k=\frac{2.303}{t}\log\frac{[A_o]}{[A]}](https://tex.z-dn.net/?f=k%3D%5Cfrac%7B2.303%7D%7Bt%7D%5Clog%5Cfrac%7B%5BA_o%5D%7D%7B%5BA%5D%7D)
where,
k = rate constant = ?
t = time taken = 440 s
= initial amount of the reactant = 0.50 M
[A] = left amount = 0.20 M
Putting values in above equation, we get:


The equation used to calculate half life for first order kinetics:

Putting values in this equation, we get:

Therefore, the half-life of a first-order reaction is, 
The early hypothesis of Alfred wegener was based on observations that suggested continents were once joined together. later the theory of plate tectonics explained why large pieces of earths surfaces moves around and how many of earths features form.
but i this case c. continental drift and plate tectonics
Answer:
68.3 kilo Pascal is the pressure in the container.
Explanation:
To calculate the new pressure , we use the equation given by Boyle's law. This law states that pressure is inversely proportional to the volume of the gas at constant temperature.
The equation given by this law is:

where,
are initial pressure and volume.
are final pressure and volume.
We are given:

Putting values in above equation, we get:


68.3 kilo Pascal is the pressure in the container.
The –OH+ group is most acidic proton in ln-OH as shown in figure (a). The proton is circled in the figure.
The stabilisation of the conjugate base produced is stabilises due to resonance factor. The possible resonance structures are shown in figure (b).
The acidity of a protonated molecule depends upon the stabilisation of the conjugate base produced upon deprotonation. The conjugate base of ln-OH is shown in figure (a).
The possible resonance structures are shown in figure (b). As the number of resonance structures of the conjugate base increases the stabilisation increases. Here the unstable quinoid (unstable) form get benzenoid (highly stable) form due to the resonance which make the conjugate base highly stabilise.
Thus the most acidic proton is assigned in ln-OH and the stability of the conjugate base is explained.