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masha68 [24]
3 years ago
6

A balloon is filled to a volume of 1.50 L with 3.00 moles of gas at 25 °C. With pressure and temperature held constant, what wil

l be the volume (in L) of the balloon if 0.50 moles of gas are released?
Chemistry
1 answer:
Ludmilka [50]3 years ago
6 0

Answer:

Volume : 1.25 L

Explanation:

We are given here that the volume ( V_1 ) = 1.50 Liters, the initial moles ( held at 25 °C ) = 3.00 mol, and the final moles ( n_2 ) = 3.00 - 0.5 = 2.5 mol. The final mol is calculated given that 0.50 mol of gas are released from the prior 3.00 moles of gas.

Volume ( V_1 ) = 1.50 L,

Initial moles ( n_1 ) = 3.00 mol,

Final Volume ( n_2 ) = 3.00 - 0.5 = 2.5 mol

Applying the combined gas law, we can calculate the final volume ( V_2 ).

P_1V_1 / n_1T_1 = P_2V_2 / n_2T_2 - we know that the pressure and temperature are constant, and therefore we can apply the following formula,

V_1 / n_1 = V_2 / n_2 - isolate V_2,

V_2 = V_1 n_2 / n_1 = 1.50 L * 2.5 mol / 3.00 mol = ( 1.5 * 2.5 / 3 ) L = 1.25 L

The volume of the balloon will be 1.25 L.

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or,        p_{total} = p_{1} + p_{2} + p_{3} + p_{4} + ......... + p_{n}

where,  p_{1}, p_{2}, p_{3} ....... = partial pressure of individual gases present in the mixture

Also, relation between partial pressure and mole fraction is as follows.

                 p_{i} = p_{total} \times x_{i}

where,      x_{i} = mole fraction

Thus, we can conclude that the statement Dalton's law of partial pressures states that the total pressure exerted by a mixture of gases is the sum of the pressures exerted independently by each gas in the mixture, is true.              

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When nitrogen dioxide (NO2) from car exhaust combines with water in the air, it forms nitric acid (HNO3), which causes acid rain
yKpoI14uk [10]

<u>Answer:</u>

<u>For a:</u> The number of molecules of nitrogen dioxide is 4.52\times 10^{23}

<u>For b:</u> The mass of nitric acid formed is 54.81 grams

<u>For c:</u> The mass of nitric acid formed is 206 grams

<u>Explanation:</u>

The given chemical reaction follows:

3NO_2(g)+H_2O(l)\rightarrow 2HNO_3(aq.)+NO(g)

  • <u>For a:</u>

By Stoichiometry of the reaction:

1 mole of water reacts with 3 moles of nitrogen dioxide

So, 0.250 moles of water will react with \frac{3}{1}\times 0.250=0.75mol of nitrogen dioxide

According to mole concept:

1 mole of a compound contains 6.022\times 10^{23} number of molecules.

So, 0.75 moles of nitrogen dioxide will contain 0.75\times 6.022\times 10^{23}=4.52\times 10^{23} number of molecules

Hence, the number of molecules of nitrogen dioxide is 4.52\times 10^{23}

  • <u>For b:</u>

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}     .....(1)

Given mass of nitrogen dioxide = 60.0 g

Molar mass of nitrogen dioxide = 46 g/mol

Putting values in equation 1, we get:

\text{Moles of nitrogen dioxide}=\frac{60.0g}{46g/mol}=1.304mol

By Stoichiometry of the reaction:

3 moles of nitrogen dioxide produces 2 mole of nitric acid

So, 1.304 moles of nitrogen dioxide will produce = \frac{2}{3}\times 1.304=0.870 moles of nitric acid

Now, calculating the mass of nitric acid from equation 1, we get:

Molar mass of nitric acid = 63 g/mol

Moles of nitric acid = 0.870 moles

Putting values in equation 1, we get:

0.870mol=\frac{\text{Mass of nitric acid}}{63g/mol}\\\\\text{Mass of nitric acid}=(0.870mol\times 63g/mol)=54.81g

Hence, the mass of nitric acid formed is 54.81 grams

  • <u>For c:</u>
  • <u>For nitrogen dioxide:</u>

Given mass of nitrogen dioxide = 225 g

Molar mass of nitrogen dioxide = 46 g/mol

Putting values in equation 1, we get:

\text{Moles of nitrogen dioxide}=\frac{225g}{46g/mol}=4.90mol

  • <u>For water:</u>

Given mass of water = 55.2 g

Molar mass of water = 18 g/mol

Putting values in equation 1, we get:

\text{Moles of water}=\frac{55.2g}{18g/mol}=3.06mol

By Stoichiometry of the reaction:

3 moles of nitrogen dioxide reacts with 1 mole of water

So, 4.90 moles of nitrogen dioxide will react with = \frac{1}{3}\times 4.90=1.63mol of water

As, given amount of water is more than the required amount. So, it is considered as an excess reagent.

Thus, nitrogen dioxide is considered as a limiting reagent because it limits the formation of product.

By Stoichiometry of the reaction:

3 mole of nitrogen dioxide produces 2 moles of nitric acid

So, 4.90 moles of nitrogen dioxide will produce \frac{2}{3}\times 4.90=3.27mol of nitric acid

Now, calculating the mass of nitric acid from equation 1, we get:

Molar mass of nitric acid = 63 g/mol

Moles of nitric acid = 3.27 moles

Putting values in equation 1, we get:

3.27mol=\frac{\text{Mass of nitric acid}}{63g/mol}\\\\\text{Mass of nitric acid}=(3.27mol\times 63g/mol)=206g

Hence, the mass of nitric acid formed is 206 grams

7 0
2 years ago
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