a = Proton transfer d = SN2 Nucleophilic substitution g = Nucleophilic subs at carbonyl(acyl Xfer) b = Lewis acid/base e= Electr
ophilic aromatic substitution h = Conjugate (nucleophilic) addn c = E2 elimination f = Carbonyl nucleophilic addn Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. n(nh3)3
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Answer:
Explanation:
The Gibbs free energy in thermodynamics is a potential which is used to calculate maximum of the reversible work which is performed by a specific thermodynamic system at constant temperature (isothermal) as well as pressure (isobaric).
The expression for the change in free energy is:
Answer:
The effective nuclear charge for a valence electron in oxygen atom:
Explanation:
Effective nuclear charge is the net nuclear charge experienced by the electron in a given atom. It is always less than the actual charge of the nucleus [Z], due to shielding by electrons in the inner shells.
<em>It is equal to the difference between the actual nuclear charge or the atomic number (Z) and the shielding constant (s). </em>
<u>For an oxygen atom</u>-
Electron configuration: (1s²) (2s² 2p⁴)
<em>The atomic number (actual nuclear charge): </em>Z = 8
The shielding constant (s) for a valence electron can be calculated by using the Slater's rules:
⇒ s = 5 × 0.35 + 2 × 0.85 = 1.75 + 1.7 = 3.45
<u><em>Therefore, the effective nuclear charge for a valence electron in oxygen atom is:</em></u>
<u>Therefore, the effective nuclear charge for a valence electron in oxygen atom:</u>