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Answer:
the final volume of the gas is = 1311.5 mL
Explanation:
Given that:
a sample gas has an initial volume of 61.5 mL
The workdone = 130.1 J
Pressure = 783 torr
The objective is to determine the final volume of the gas.
Since the process does 130.1 J of work on its surroundings at a constant pressure of 783 Torr. Then, the pressure is external.
Converting the external pressure to atm ; we have
External Pressure :
The workdone W = V
The change in volume ΔV=
ΔV =
ΔV =
ΔV = 1.25 L
ΔV = 1250 mL
Recall that the initial volume = 61.5 mL
The change in volume V is
multiply through by (-), we have:
= 1250 mL + 61.5 mL
= 1311.5 mL
∴ the final volume of the gas is = 1311.5 mL
Explanation:
Half life of zero order and second order depends on the initial concentration. But as the given reaction slows down as the reaction proceeds, therefore, it must be second order reaction. This is because rate of reaction does not depend upon the initial concentration of the reactant.
a. As it is a second order reaction, therefore, doubling reactant concentration, will increase the rate of reaction 4 times. Therefore, the statement a is wrong.
b. Expression for second order reaction is as follows:
the above equation can be written in the form of Y = mx + C
so, the plot between 1/[A] and t is linear. So the statement b is true.
c.
Expression for half life is as follows:
As half-life is inversely proportional to initial concentration, therefore, increase in concentration will decrease the half life. Therefore statement c is wrong.
d.
Plot between A and t is exponential, therefore there is no constant slope. Therefore, the statement d is wrong