presence of heat can change solid tu liquid
and liquid to gas
Answer: Option (d) is the correct answer.
Explanation:
Steps involved for the given reaction will be as follows.
Step 1:
(fast)
Rate expression for step 1 is as follows.
Rate = k ![[NO]^{2}](https://tex.z-dn.net/?f=%5BNO%5D%5E%7B2%7D)
Step 2: 
This step 2 is a slow step. Hence, it is a rate determining step.
Step 3.
(fast)
Here,
is intermediate in nature.
All the steps are bimolecular and it is a second order reaction. Also, there is no catalyst present in this reaction.
Thus, we can conclude that the statement step 1 is the rate determining step, concerning this mechanism is not directly supported by the information provided.
Most transition metal form more than one cation but aluminum forms the Al3+ cation only.
<u>Answer: </u>The equation which is wrong is 
<u>Explanation:</u>
For the given reaction:

The expression for
is given by:
![K_c=\frac{1}{[O_2]^3}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B1%7D%7B%5BO_2%5D%5E3%7D)
![K_p=\frac{1}{[O_2]^3}](https://tex.z-dn.net/?f=K_p%3D%5Cfrac%7B1%7D%7B%5BO_2%5D%5E3%7D)
The concentration of solids are taken to be 1, only concentration of gases and liquid states are taken. The pressure of only gases are taken.
Relationship between
is given by the expression:

where,
= number of moles of gaseous products - number of moles of gaseous reactants
R = gas constant
T= temperature
For the above reaction,
= number of moles of gaseous products - number of moles of gaseous reactants = 0 - 3 = -3
Hence, the expression for
is:

Therefore, the equation which is wrong is 