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LekaFEV [45]
3 years ago
9

Be sure to answer all parts.The equilibrium constant, Kc, for the formation of nitrosyl chloride from nitric oxide and chlorine,

2NO(g) + Cl2(g) ⇌ 2NOCl(g)is 6.5 ×104 at 35°C. Calculate KP for this reaction, and determine whether the reaction will proceed to the right or to the left to achieve equilibrium when the starting pressures are PNO = 1.01 atm, PCl2 = 0.42 atm, and PNOCl = 1.76 atm.×10(Enter your answer in scientific notation.)reaction will proceed to the rightreaction is at equilibriumreaction will proceed to the left
Chemistry
1 answer:
djverab [1.8K]3 years ago
4 0

<u>Answer:</u> The reaction proceeds in the forward direction

<u>Explanation:</u>

For the given chemical equation:

2NO(g)+Cl_2(g)\rightleftharpoons 2NOCl(g)

Relation of K_p\text{ with }K_c is given by the formula:

K_p=K_c(RT)^{\Delta n_g}

where,

K_p = equilibrium constant in terms of partial pressure = ?

K_c = equilibrium constant in terms of concentration = 6.5\times 10^4

R = Gas constant = 0.0821\text{ L atm }mol^{-1}K^{-1}

T = temperature = 35^oC=[35+273]K=308K

\Delta n_g = change in number of moles of gas particles = n_{products}-n_{reactants}=2-3=-1

Putting values in above equation, we get:

K_p=6.5\times 10^4\times (0.0821\times 500)^{-1}\\\\K_p=1583.43

K_p is the constant of a certain reaction at equilibrium while Q_p is the quotient of activities of products and reactants at any stage other than equilibrium of a reaction.

The expression of Q_p for above equation follows:

Q_p=\frac{(p_{NOCl})^2}{p_{Cl_2}\times (p_{NO})^2}

We are given:

p_{NOCl}=1.76atm

p_{NO}=1.01atm

p_{Cl_2}=0.42atm

Putting values in above equation, we get:

Q_p=\frac{(1.76)^2}{0.42\times (1.01)^2}=7.23

We are given:

K_p=1583.43

There are 3 conditions:

  • When K_{p}>Q_p; the reaction is product favored.
  • When K_{p}; the reaction is reactant favored.
  • When K_{p}=Q_p; the reaction is in equilibrium

As, K_p>Q_p, the reaction will be favoring product side.

Hence, the reaction proceeds in the forward direction

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Air containing 0.04% carbon dioxide is pumped into a room whose volume is 6000 ft3. The air is pumped in at a rate of 2000 ft3/m
koban [17]

Here is the full question:

Air containing 0.04% carbon dioxide is pumped into a room whose volume is 6000 ft3. The air is pumped in at a rate of 2000 ft3/min, and the circulated air is then pumped out at the same rate. If there is an initial concentration of 0.2% carbon dioxide, determine the subsequent amount in the room at any time.

What is the concentration at 10 minutes? (Round your answer to three decimal places.

Answer:

0.046 %

Explanation:

The rate-in;

R_{in} = \frac{0.04}{100}*2000

R_{in} = 0.8

The rate-out

R_{out} = \frac{A}{6000}*2000

R_{out} = \frac{A}{3}

We can say that:

\frac{dA}{dt}= 0.8-\frac{A}{3}

where;

A(0)= 0.2% × 6000

A(0)= 0.002 × 6000

A(0)= 12

\frac{dA}{dt} +\frac{A}{3} =0.8

Integration of the above linear equation =

e^{\int\limits \frac {1}{3}dt } = e^{\frac{1}{3}t

so we have:

e^{\frac{1}{3}t}\frac{dA}{dt}} +\frac{1}{3}e^{\frac{1}{3}t}A = 0.8e^{\frac{1}{3}t

\frac{d}{dt}[e^{\frac{1}{3}t}A] = 0.8e^{\frac{1}{3}t

Ae^{\frac{1}{3}t} =2.4e\frac{1}{3}t +C

∴ A(t) = 2.4 +Ce^{-\frac{1}{3}t

Since A(0) = 12

Then;

12 =2.4 + Ce^{-\frac{1}{3}}(0)

C= 12-2.4

C =9.6

Hence;

A(t) = 2.4 +9.6e^{-\frac{t}{3}}

A(0) = 2.4 +9.6e^{-\frac{10}{3}}

A(t) = 2.74

∴ the concentration at 10 minutes is ;

=  \frac{2.74}{6000}*100%

= 0.0456667 %

= 0.046% to three decimal places

7 0
3 years ago
An analytical chemist is titrating 118.3 mL of a 0.3500 M solution of butanoic acid (HC3H7CO2) with a 0.400 M solution of KOH. T
TEA [102]

Answer:

pH = 12.33

Explanation:

Lets call HA = butanoic acid and A⁻ butanoic acid and its conjugate base butanoate respectively.

The titration reaction is

HA + KOH ---------------------------- A⁻ + H₂O + K⁺

number of moles of HA :   118.3 ml/1000ml/L x 0.3500 mol/L = 0.041 mol HA

number of  moles of OH  : 115.4 mL/1000ml/L x 0.400 mol/L  = 0.046 mol A⁻

therefore the weak acid will be completely consumed and what we have is  the unreacted strong base KOH which will drive the pH of the solution since the contribution of the conjugate base is negligible.

n unreacted KOH = 0.046 - 0.041 = 0.005 mol KOH

pOH = - log (KOH)

M KOH = 0.005 mol / (0.118.3 +0.1154)L = 0.0021 M

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pH = 14 - 1.96 = 12.33

Note: It is a mistake to ask for the pH of the <u>acid solutio</u>n since as the above calculation shows we have a basic solution the moment all the acid has been consumed.

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Answer:236.6

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