You can tell if each side of the equation has the same molar mass.
It has to be understood that 2 moles of oxygen are there in each mole of PbO2. Then it has to be calculated for 2 moles of oxygen.
Amount of oxygen = 2 * 5.43 moles
= 10.86 moles
Now it is also a fact that each mole of H2O contains 1 mole of oxygen. Then it can be easily concluded that 10.86 moles of water will be produced. I hope the procedure is clear enough for you to understand.
Answer:
It is heterogeneous as it is made up of visibly different substances or phases.
Ca + 2HCl = CaCl₂ + H₂
c=4.50 mol/l
v=2.20 l
n(HCl)=cv
m(Ca)/M(Ca)=n(HCl)/2
m(Ca)=M(Ca)cv/2
m(Ca)=40g/mol·4.50mol/l·2.20l/2=198 g
198 grams of Ca are needed