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Answer:
The given molecules are SO2 and BrF5.
Explanation:
Consider the molecule SO2:
The central atom is S.
The number of domains on S in this molecule is three.
Domain geometry is trigonal planar.
But there is a lone pair on the central atom.
So, according to VSEPR theory,
the molecular geometry becomes bent or V-shape.
Hybridization on the central atom is
.
Consider the molecule BrF5:
The central atom is Br.
The number of domains on the central atom is six.
Domain geometry is octahedral.
But the central atom has a lone pair of electrons.
So, the molecular geometry becomes square pyramidal.
The hybridization of the central atom is .
The shapes of SO2 and BrF5 are shown below:
Answer: 20.7 kJ
Explanation:
According to first law of thermodynamics:
=Change in internal energy
q = heat absorbed or released
w = work done or by the system
w = work done on the system= {Work is done on the system is positive as the final volume is lesser than initial volume}
w = 4.51 kcal = (1kcal = 4.184kJ)
q = +1.79 kJ {Heat absorbed by the system is positive}
Thus for a system that receives 1.79 kJ of heat from surroundings and has 4.51 kcal of work done on it at the same time is 20.7 kJ