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Maslowich
3 years ago
10

Explain why all glassware must be dry and the solvent anhydrous during formation and reaction of a grignard reaction. Further, e

xplain whether acetone would be a viable solvent for generation of a grignard reagent. Include one or more balanced chemical equations in your answer.
Chemistry
1 answer:
mario62 [17]3 years ago
7 0

Answer:

The glassware and solvent for the production of grignard reagent and its reaction should by dry and anhydrous so as to prevent the conversion of the grignard reagent into saturated alkane. Acetone, is not a good solvent for the generation of grignard reagent because it has the potential of forming alcohol.

Explanation:

Grignard reagent is a compound formed by the reaction of halide of alkyl or alkene with magnesium metal. This makes the compound more nucleophilic. Thus the availability of an electrophile around it will evoke a quick reaction. The presence of water in an acidic condition will generate hydroxonium ions which are highly electrophilic. There will therefore be an introduction of hydrogen ions to the grignard reagent and which will displace the MgBr leading to the formation of alkane.

Acetone tends to produce alcohol when they are exposed to grignard reagent, thus they are not appropriate to be used as solvent. This is due to the resultant highly electrophilic nature of the carbonyl carbon on the acetone, thus will react with the nucleophilic carbon on the grignard. The reaction can be represented as follows:

RMgBr + CH3(CO)CH3 + H (with hydrogen ions) >>>RCOH + Mg(OH)Br

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How is the periodic table arranged
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8 0
3 years ago
If we add a catalyst to the following equation, CO + H2O + heat CO2 + H2, which way will the equilibrium shift?
Igoryamba

Answer:

No effect.

Explanation:

Hello,

In this case, considering the widely studied Le Chatelier's principle, we can realize that the factors affecting equilibrium are concentration, temperature and pressure and volume if the reaction is in gaseous phase and with non-zero change in the number of moles. In such a way, by adding a catalyst to given reaction will have no effect on the equilibrium direction.

Best regards.

7 0
3 years ago
If 1.8 L of water is added to 2.5 L of a 7.0 M KOH solution, what is the molarity of the new solution?
e-lub [12.9K]
Molarity= (number of moles of that substance) / (Volume of solution in litres)

7= (number of moles of HCl) / 0.05

Thus,

Number of moles of HCl = 7 x 0.05 = 0.35

The number of moles of HCl will remain unchanged.

Now, for new solution,

0.35= 0.35 / (New volume of solution in litres)

Thus,

New volume = 1 litre

Thus, amount of water added = 1- 0.05 litre = 5.0 M

6 0
3 years ago
Arrange the following substance into acid,base and neutral. sodium chloride, tomato juice, vinegar,sea water,bicorbonate of sodi
pantera1 [17]

Answer:

sodium chloride: neutral.

tomato juice: acid.

vinegar: acid.

sea water: base.

bicarbonate of sodium​: base.

Explanation:

Hello there!

In this case, in agreement to the definition of the pH, as the measure of the acidity and basicity of a substance; it is important to recall that pH's below 7 stand for acidic substances and pH's above 7 stand for basic substances, whereas a pH of 7 defines a neutral one. In such a way, given the pH's of the given substances, 7, 4.05 to 4.65, around 2.5, about 8.1 and about 8.3 respectively for sodium chloride, tomato juice, vinegar, sea water, bicarbonate of sodium​, it is possible to assert:

sodium chloride: neutral.

tomato juice: acid.

vinegar: acid.

sea water: base.

bicarbonate of sodium​: base.

Best regards!

3 0
3 years ago
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