1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
Maslowich
3 years ago
10

Explain why all glassware must be dry and the solvent anhydrous during formation and reaction of a grignard reaction. Further, e

xplain whether acetone would be a viable solvent for generation of a grignard reagent. Include one or more balanced chemical equations in your answer.
Chemistry
1 answer:
mario62 [17]3 years ago
7 0

Answer:

The glassware and solvent for the production of grignard reagent and its reaction should by dry and anhydrous so as to prevent the conversion of the grignard reagent into saturated alkane. Acetone, is not a good solvent for the generation of grignard reagent because it has the potential of forming alcohol.

Explanation:

Grignard reagent is a compound formed by the reaction of halide of alkyl or alkene with magnesium metal. This makes the compound more nucleophilic. Thus the availability of an electrophile around it will evoke a quick reaction. The presence of water in an acidic condition will generate hydroxonium ions which are highly electrophilic. There will therefore be an introduction of hydrogen ions to the grignard reagent and which will displace the MgBr leading to the formation of alkane.

Acetone tends to produce alcohol when they are exposed to grignard reagent, thus they are not appropriate to be used as solvent. This is due to the resultant highly electrophilic nature of the carbonyl carbon on the acetone, thus will react with the nucleophilic carbon on the grignard. The reaction can be represented as follows:

RMgBr + CH3(CO)CH3 + H (with hydrogen ions) >>>RCOH + Mg(OH)Br

You might be interested in
A possible mechanism for the gas phase reaction of NO and H2 is as follows: Step 1 2NO N2O2 Step 2 N2O2 + H2 N2O + H2O Step 3 N2
mel-nik [20]

Answer: Option (d) is the correct answer.

Explanation:

Steps involved for the given reaction will be as follows.

Step 1: 2NO \Leftrightarrow N_{2}O_{2}    (fast)

Rate expression for step 1 is as follows.

               Rate = k [NO]^{2}

Step 2: N_{2}O_{2} + H_{2} \rightarrow N_{2}O + H_{2}O

This step 2 is a slow step. Hence, it is a rate determining step.

Step 3. N_{2}O + H_{2} \rightarrow N_{2} + H_{2}O    (fast)

Here, N_{2}O_{2} is intermediate in nature.

All the steps are bimolecular and it is a second order reaction. Also, there is no catalyst present in this reaction.

Thus, we can conclude that the statement step 1 is the rate determining step, concerning this mechanism is not directly supported by the information provided.

4 0
3 years ago
A compound has the empirical formula . a 256-ml flask, at 373 k and 750. torr, contains 0.527 g of the gaseous compound. give th
CaHeK987 [17]
<span>Answer: From the ideal gas law, MM=mRTPV; where MM = molecular mass; m = mass; P = pressure in atmospheres; V= volume in litres; R = gas constant with appropriate units. So, 0.800â‹…gĂ—0.0821â‹…Lâ‹…atmâ‹…Kâ’1â‹…molâ’1Ă—373â‹…K0.256â‹…LĂ—0.987â‹…atm = 97.0 gâ‹…molâ’1. nĂ—(12.01+1.01+2Ă—35.45)â‹…gâ‹…molâ’1 = 97.0â‹…gâ‹…molâ’1. Clearly, n = 1. And molecular formula = C2H2Cl2. I seem to recall (but can't be bothered to look up) that vinylidene chloride, H2C=C(Cl)2 is a low boiling point gas, whereas the 1,2 dichloro species is a volatile liquid. At any rate we have supplied the molecular formula as required.</span>
4 0
3 years ago
Do oxygen atoms become more stable or less stable when oxygen forms compounds? Explain
4vir4ik [10]
They become more stable because they achieve a full outer shell of valence electrons with the magic number of 8.

5 0
2 years ago
Read 2 more answers
Write the symbol for every chemical element that has an atomic number less than 13 and atomic mass greater than 19.3 u
emmainna [20.7K]

Answer:

The symbol of each element is, Ne, Na, Mg, and Al.

Explanation:

Below is the list of elements that has an atomic mass of less than 19.3 u.

The atomic mass of Neon is 20.1797 u and the atomic number is 10.

The atomic mass of Sodium is 22.989769 u and the atomic number is 11.

The atomic mass of Magnesium is 24.305 u and the atomic number is 12.

The atomic mass of Aluminium is 26.981539 u and the atomic number is 13.

Here, the symbol of each element is, Ne, Na, Mg, and Al.

3 0
3 years ago
The gold foil experiment resulted in two major discoveries which were made about the structure of the atom. what were they
DanielleElmas [232]
It showed that the nucleus is positively charged, and that the atom isn't just made of electrons.
8 0
3 years ago
Other questions:
  • An article about half-lives describes a daughter isotope. What is a daughter isotope?
    15·2 answers
  • To pull up a bucket of water from a well, George pulled hard on a handle to wind up a rope. Which kind of energy was George appl
    13·1 answer
  • 20 POINTS PLZ ANSWER FAST !!!!!!!!!!!!!!!!!!
    7·1 answer
  • Calculate the number of formula units in 1.87 mol of NH4Cl
    12·1 answer
  • →
    9·1 answer
  • How many elements are in this chemical formula? <br> 2(NH4)2SO4
    7·1 answer
  • NEED HELP ASAP
    13·1 answer
  • Please help me with these questions please...
    15·1 answer
  • The given reaction is second order with respect to A, first order with respect to B and zero order with
    7·1 answer
  • Cobalt-59 is the only stable isotope of this transition metal. One ⁵⁹Co atom has a mass of 58.933198 amu. Calculate the binding
    11·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!