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alexandr402 [8]
3 years ago
13

For a reaction, a plot of ln K versus inverse temperature is found to be linear and fits the following equation: y = -1,498x + 7

.14. What is the value of ΔH? Give your answer with units of kJ/molK; however, you should not type in the units
Chemistry
1 answer:
Harrizon [31]3 years ago
4 0

Answer:

12.455 KJ/molK = ΔH

Explanation:

One way to write Van't Hoff equation is:

lnK = -ΔH / RT + ΔS/R

<em>Where R is gas constant (8.314472 J/molK)</em>

The graph of lnK vs 1/T has as slope -ΔH / R and as intercept ΔS/R

If in the graph you obtain the equation:

y = -1,498x + 7.14

-1,498 =  -ΔH / R

-1,498×8.314472J/molK =  -ΔH

12455 J/molK = ΔH

<em>12.455 KJ/molK = ΔH</em>

<em></em>

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Answer:

850g/min

Explanation:

The reaction expression is given as:

      P₄  +  5O₂   →   P₄O₁₀

Given that:

Number of moles of product  = 1.5moles

Time  = 30s = 0.5min

Unknown:

The rate of the reaction  = ?

Solution:

Convert the moles given to mass of the product.

     So;

     Mass of product  = number of moles x molar mass

Molar mass of P₄O₁₀   = 4(31) + 10(16)  = 284g/mol

    Mass of product  = 1.5moles x 284g/mol  = 426g

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 Reaction rate  = \frac{mass of product}{time}   = \frac{426}{0.5}   = 850g/min

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Explanation:

To solve this problem, it is important to first determine the balanced chemical equation. The balanced equation is necessary as it will provide the mole-to-mole ratio needed to convert between moles O₂ and moles H₂O.

The unbalanced equation:

C₈H₁₈ (l) + O₂ (g) ---> CO₂ (g) + H₂O (g)

<u>Reactants:</u> 8 carbon, 18 hydrogen, 2 oxygen

<u>Products:</u> 1 carbon, 2 hydrogen, 3 oxygen

As you can see, the equation is not balanced because there are unequal amounts of each element on both sides. Balancing the equation is a matter of guessing-and-checking to see which combination of coefficients work.

The balanced equation:

2 C₈H₁₈ (l) + 25 O₂ (g) ---> 16 CO₂ (g) + 18 H₂O (g)

<u>Reactants:</u> 16 carbon, 36 hydrogen, 50 oxygen

<u>Products:</u> 16 carbon, 36 hydrogen, 50 oxygen

Now that the equation is balanced, we can use the coefficients of O₂ and H₂O to construct our mole-to-mole ratio and perform our conversion. The final answer should have 2 sig figs to match the given value (1.2 moles). The state of matter is most likely not necessary to include in your final answer.

1.2 moles O₂          18 moles H₂O
---------------------  x  -----------------------  =  0.86 moles H₂O
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