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Yakvenalex [24]
3 years ago
15

In a unimolecular reaction with seven times as much starting material as product at equilibrium, what is the value of keq?

Chemistry
1 answer:
Kitty [74]3 years ago
6 0

<em>K</em>_eq = 0.14

The chemical equation is  

A ⇌ B

The equilibrium constant expression is

<em>K</em>_eq = [B]/[A]

If [A] = 7[B]

<em>K</em>_eq = [B]/{7[B]}= 1/7 = 0.14

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Calculate the pH of a solution that contains 2.7 M HF and 2.7 M HOC6H5. Also, calculate the concentration of OC6H5- in this solu
borishaifa [10]

Answer:

\large \boxed{\mathbf{1.36; 3.6 \times 10^{\mathbf{-9}}}\textbf{mol/L}}

Explanation:

The HF is about five million times as strong as phenol, so it will be by far the major contributor of hydronium ions. We can ignore the contribution from the phenol.

1 .Calculate the hydronium ion concentration

We can use an ICE table to organize the calculations.

                    HF + H₂O ⇌ H₃O⁺ + F⁻

I/mol·L⁻¹:       2.7                   0       0

C/mol·L⁻¹:      -x                   +x      +x

E/mol·L⁻¹:   2.7 - x                 x        x

K_{\text{a}} = \dfrac{\text{[H}_{3}\text{O}^{+}] \text{F}^{-}]} {\text{[HF]}} = 7.2 \times 10^{-4}\\\\\dfrac{x^{2}}{2.7 - x} = 7.2 \times 10^{-4}\\\\\text{Check for negligibility of }x\\\\\dfrac{2.7}{7.2 \times 10^{-4}} = 4000 > 400\\\\\therefore x \ll 2.7\\\dfrac{x^{2}}{2.7} = 7.2 \times 10^{-4}\\\\x^{2} = 2.7 \times 7.2 \times 10^{-4} = 1.94 \times 10^{-3}\\x = 0.0441\\\text{[H$_{3}$O$^{+}$]}= \text{x mol$\cdot$L$^{-1}$} = \text{0.0441 mol$\cdot$L$^{-1}$}

2. Calculate the pH

\text{pH} = -\log{\rm[H_{3}O^{+}]} = -\log{0.0441} = \large \boxed{\mathbf{1.36}}

3. Calculate [C₆H₅O⁻]

C₆H₅OH + H₂O ⇌ C₆H₅O⁻ + H₃O⁺

     2.7                         x        0.0441

K_{\text{a}} = \dfrac{0.0441x} {2.7} = 1.6 \times 10^{-10}\\\\0.0441x = 1.6 \times 10^{-10}\\x = \dfrac{1.6 \times 10^{-10}}{0.0441} = \mathbf{3.6 \times 10^{\mathbf{-9}}}\textbf{ mol/L}\\\text{The concentration of phenoxide ion is $\large \boxed{\mathbf{3.6 \times 10^{\mathbf{-9}}}\textbf{ mol/L}}$}

6 0
3 years ago
Complete the paragraph about the formation of sodium phosphide.
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<h2>Let us complete it :</h2>

Explanation:

let us study about formation of sodium phosphide

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A tone that is lower in pitch is lower in what characteristic?
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A tone that is lower in pitch is lower in what characteristic?=frequency
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A
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Answer:

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