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Valentin [98]
3 years ago
14

A solution has a (oh-) = 8.6 × 10-5 the poh=, ph=, (h+)=

Chemistry
1 answer:
nalin [4]3 years ago
6 0
POh is calculated by the negative logarithm of hydroxide ions concentration. From the given value, we have:

<span>pOH = -log(8.6 x 10 ^-5)
</span><span>pOH = 4.07
</span><span>
To calculate the pH we use the relation of pOH and pH, expressed as:
</span><span>
14 = pOH + pH
</span><span>pH = 14 - 4.07 = 9.93
</span><span>pH = -log [H+]
</span><span>[H+] = 10^-9.93 = 1.16 x 10^-3 M</span>
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The concentration of lead ion required to just initiate precipitation is -2.37\times10^-^5 M

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Lets calculate -:

Solubility equilibrium -: PbI_2(s) ⇄ Pb^2^+ (aq) + 2I^- (aq)

Solubility product of PbI_2 ,Q=[Pb^2^+]_i_n_i_t_i_a_l [I^-]^2_i_n_i_t_i_a_l =9.8\times10^-^9

Concentration of I^-=[KI]=0.0492M

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        [Pb^2^+]_i_n_i_t_i_a_l [I^-]^2_i_n_i_t_i_a_l \geq 9.8\times10^-^9

      [Pb^2^+]_i_n_i_t_i_a_l  [0.0492]^2 \geq 9.8\times10^-^9

                       [Pb^2^+]_i_n_i_t_i_a_l \geq \frac{9.8\times10^-^9}{[0.0492]^2}

                        [Pb^2^+]_i_n_i_t_i_a_l \geq \frac{9.8\times10^-^9}{2.42\times10^-^3}

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3 years ago
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