Answer:
The presence of 1-2% ethanol as catalyst, suppresses the oxidation of chloroform with oxygen to give a poisonous gas called phosgene. ... Here glycerol acts as negative catalyst. Criteria or characteristics of catalysts. i. The mass and chemical composition of catalyst should remain unchanged at the end of the reaction.
Explanation:
The integrated rate law for a second-order reaction is given by:
![\frac{1}{[A]t} = \frac{1}{[A]0} + kt](https://tex.z-dn.net/?f=%20%5Cfrac%7B1%7D%7B%5BA%5Dt%7D%20%3D%20%20%20%5Cfrac%7B1%7D%7B%5BA%5D0%7D%20%2B%20kt%20)
where, [A]t= the concentration of A at time t,
[A]0= the concentration of A at time t=0
<span>k =</span> the rate constant for the reaction
<u>Given</u>: [A]0= 4 M, k = 0.0265 m–1min–1 and t = 180.0 min
Hence, ![\frac{1}{[A]t} = \frac{1}{4} + (0.0265 X 180)](https://tex.z-dn.net/?f=%20%5Cfrac%7B1%7D%7B%5BA%5Dt%7D%20%3D%20%5Cfrac%7B1%7D%7B4%7D%20%2B%20%280.0265%20X%20180%29%20)
<span> = 4.858</span>
<span><span><span>Therefore, [A]</span>t</span>= 0.2058 M.</span>
<span>
</span>
<span>Answer: C</span>oncentration of A, after 180 min, is 0.2058 M
C-12? (6 protons) C-13? (6 protons) C-14? (6 protons)
Answer:
Explanation:
When an electron jumps from one energy level to a lower energy level some energy is released in the form of a photon.
The difference in energy between the two levels is the energy of the photon and that energy is related to the frequency of the photon by the Einstein - Planck equation:
Where,
- E = energy of the photon,
- h = 6.626×10⁻³⁴ J.s, Planck constant, and
- ν = frequency of the photon.
So, to find the frequency you must first find the energy.
The transition energy can be calculated using the formula:
Where E₀ = 13.6 eV ( 1 eV = 1.602×10⁻¹⁹ Joules) and n = 1,2,3,...
So, the transition energy between n = 4 and n = 3 will be:
- ΔE = - E₀ [ 1/4² - 1/3²] = - 13.6 eV [1/16 - 1/9] = 0.6611. . .eV
- ΔE = 1.602×10⁻¹⁹ Joules/eV × 0.6611... eV = 1.0591 ×10⁻¹⁹ Joules
Now you can use the Einstein - Planck equation:
- ν = 1.0591 ×10⁻¹⁹ J / 6.626×10⁻³⁴ J.s = 1.60×10¹⁴ s⁻¹ (rounded to 3 significant figures).
Calorimetry-the science or act of measuring changes in state variables of a body for the purpose of deriving heat transfer associated with changes of its due date.
