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Viefleur [7K]
3 years ago
15

You have a ballon filled with hydrogen gas which keeps it at a constant pressure, regardless the volume. The initial volume of t

he gas is 736 mL at 15.0 C. The gas is heated until it’s volume is 2.28 L, what is it’s final temperature in degree Celsius
Chemistry
1 answer:
abruzzese [7]3 years ago
7 0

Answer:

619°C

Explanation:

Given data:

Initial volume of gas = 736 mL

Initial temperature = 15.0°C

Final volume of gas = 2.28 L

Final temperature = ?

Solution:

Initial volume of gas = 736 mL (736mL× 1L/1000 mL = 0.736 L)

Initial temperature = 15.0°C (15+273 = 288 K)

The given problem will be solve through the Charles Law.

According to this law, The volume of given amount of a gas is directly proportional to its temperature at constant number of moles and pressure.

Mathematical expression:

V₁/T₁ = V₂/T₂

V₁ = Initial volume

T₁ = Initial temperature

V₂ = Final volume  

T₂ = Final temperature

Now we will put the values in formula.

V₁/T₁ = V₂/T₂

T₂ = T₁V₂/V₁  

T₂ = 2.28 L × 288 K / 0.736 L

T₂ = 656.6 L.K / 0.736 L

T₂ = 892.2 K

K to °C:

892.2 - 273.15 = 619°C

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The reaction 2NO(g)+O2(g)−→−2NO2(g) is second order in NO and first order in O2. When [NO]=0.040M, and [O2]=0.035M, the observed
Oksanka [162]

Answer:

(a) The rate of disappearance of O_{2} is: 4.65*10^{-5} M/s

(b) The value of rate constant is: 0.83036 M^{-2}s^{-1}

(c) The units of rate constant is:  M^{-2}s^{-1}

(d) The rate will increase by a factor of 3.24

Explanation:

The rate of a reaction can be expressed in terms of the concentrations of the reactants and products in accordance with the balanced equation.

For the given reaction:

2NO(g)+O_{2}->2NO_{2}

rate = -\frac{1}{2} \frac{d}{dt}[NO] = -\frac{d}{dt}[O_{2}] = \frac{1}{2}\frac{d}{dt}[NO_{2}] -----(1)

According to the question, the reaction is second order in NO and first order in  O_{2}.

Then we can say that, rate = k[NO]^{2}[O_{2}] -----(2)

where k is the rate constant.

The rate of disappearance of NO is given:

-\frac{d}{dt}[NO] = 9.3*10^{-5} M/s.

(a) From (1), we can get the rate of disappearance of O_{2}.

    Rate of disappearance of  O_{2} = -\frac{d}{dt}[O_{2}] = (0.5)*(9.3*10^{-5}) M/s = 4.65*10^{-5} M/s.

(b) The rate of the reaction can be obtained from (1).

    rate = -\frac{1}{2} \frac{d}{dt}[NO] = (0.5)*(9.3*10^{-5})

    rate = 4.65*10^{-5} M/s

   The value of rate constant can be obtained by using (2).

    rate constant = k = \frac{rate}{[NO]^{2}[O_{2}]}

    k = \frac{4.65*10^{-5}}{(0.040)^{2}(0.035)} = 0.83036 M^{-2}s^{-1}

(c) The units of the rate constant can be obtained from (2).

    k = \frac{rate}{[NO]^{2}[O_{2}]}

    Substituting the units of rate as M/s and concentrations as M, we get:

\frac{Ms^{-1} }{M^{3}} = M^{-2}s^{-1}

(d) The reaction is second order in NO. Rate is proportional to square of the concentration of NO.

     rate\alpha [NO]^{2}

If the concentration of NO increases by a factor of 1.8, the rate will increase by a factor of (1.8)^{2} = 3.24

     

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Solid-solid homogeneous mixture give one example
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Titanium is a transition metal used in many alloys because it is extremely strong and lightweight. Titanium tetrachloride (TiCl4
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Answer:

a) 226.6 grams of Cl₂

b) 19.2 grams of C

c) 303.2 grams of TiCl₄ and 70.4 grams of CO₂

Explanation:

The balanced chemical reaction is the following:

TiO₂(s) + C(s) + 2 Cl₂(g) → TiCl₄(s) + CO₂(g)

(a) What mass of Cl₂ gas is needed to react with 1.60 mol TiO₂?

From the chemical equation, 1 mol of TiO₂ reacts with 2 moles of Cl₂. So, the stoichiometric ratio is 2 mol Cl₂/1 mol TiO₂. We multiply this ratio by the moles of TiO₂ we have to calculate the moles of Cl₂ we need:

1.60 mol TiO₂ x 2 mol Cl₂/1 mol TiO₂ = 3.2 mol Cl₂

Now, we convert from moles to mass by using the molecular weight (MW) of Cl₂:

MW(Cl₂) = 35.4 g/mol x 2 = 70.8 g/mol

mass of Cl₂= 3.2 mol x 70.8 g/mol = 226.6 g

<em>Therefore, 226.6 grams of Cl₂ are needed to react with 1.6 mol of TiO₂. </em>

(b) What mass of C is needed to react with 1.60 mol of TiO₂?

From the chemical equation, 1 mol of TiO₂ reacts with 1 moles of C(s). So, the stoichiometric ratio is 1 mol C/1 mol TiO₂. We multiply this ratio by the moles of TiO₂ we have to calculate the moles of C(s) we need:

1.60 mol TiO₂ x 1 mol C(s)/1 mol TiO₂ = 1.60 mol C(s)

So, we convert the moles of C(s) to grams as follows:

MW(C) = 12 g/mol

1.60 mol x 12 g/mol = 19.2 g C(s)

<em>Therefore, a mass of 19.2 grams of C is needed to react with 1.60 mol of TiO₂. </em>

(c) What is the mass of all the products formed by reaction with 1.60 mol of TiO₂?

From the chemical equation, we can notice that 1 mol of TiO₂ produces 1 mol of TiCl₄ and 1 mol of CO₂. So, from 1.60 moles of TiO₂, 1 mol of each product will be produced:

1 mol TiO₂/1 mol TiCl₄ ⇒ 1.60 mol TiO₂/1.60 mol TiCl₄

1 mol TiO₂/1 mol CO₂ ⇒ 1.60 mol TiO₂/1.60 mol CO₂

Finally, we convert the moles to grams by using the molecular weight of each compound:

MW(TiCl₄) = 47.9 g/mol Ti + (35.4 g/mol x 4 Cl) = 189.5 g/mol

1.60 mol x 189.5 g/mol = 303.2 g

MW(CO₂) = 12 g/mol C + (16 g/mol x 2 O) = 44 g/mol

1.60 mol x 44 g/mol = 70.4 g

<em>Therefore, from the reaction of 1.60 mol of TiO₂ are formed 303.2 grams of TiCl₄ and 70.4 grams of CO₂.</em>

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