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victus00 [196]
3 years ago
12

A fictitious element Z has an average atomic mass of 223.06 u.223.06 u. Element Z has two naturally occuring isotopes. The more

abundant isotope has an exact mass of 223.95 u223.95 u and a relative abundance of 65.51%.65.51%. Calculate the exact mass of the second isotope.
Chemistry
1 answer:
zhannawk [14.2K]3 years ago
5 0

Answer:

221.37 u

Explanation:

The formula for the calculation of the average atomic mass is:

Average\ atomic\ mass=(\frac {\%\ of\ the\ first\ isotope}{100}\times {Mass\ of\ the\ first\ isotope})+(\frac {\%\ of\ the\ second\ isotope}{100}\times {Mass\ of\ the\ second\ isotope})

Given that:

For first isotope:

% = 65.51 %

Mass = 223.95 u

For second isotope:

Since the element has only 2 isotopes, so the percentage of second is 100 - first percentage.

% = 100 %  - 65.51 %  = 34.49 %

Let, Mass = x u

Given, Average Mass = 223.06 u

Thus,  

223.06=\frac {65.51}{100}\times {223.95}+\frac {34.49}{100}\times {x}

Solving for x, we get that:

x = 221.37 u

<u>Thus mass of second isotope = 221.37 u</u>

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Explanation:

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         Width of Styrofoam = 24.0 cm

          Length of Styrofoam = 36.0 cm

          Height of Styrofoam = 5.0 cm

Therefore, volume of the Styrofoam will be calculated as follows.

                  Volume = length × width × height

                                =  (36.0 × 24.0 × 5.0) cm^{3}

                                 = 4320 cm^{3}

or,                             = 4.32 \times 10^{3} cm^{3}

As Styrofoam partially sinks at 3.0 cm and total height of Styrofoam is 5.0 cm. Hence, height of Styrofoam above the water is (5.0 - 3 cm) = 2 cm.

So, volume of water displaced is as follows.

          24.0 cm × 36.0 cm × 2.0 cm

         = 1.73 \times 10^{3} cm^{3}

Hence, mass of displaced water is as follows.

                 mass = density × volume

                           = 1.00 g/cm^{3} \times 1.73 \times 10^{3} cm^{3}

                           = 1.73 \times 10^{3} g

Since, book is placed on the Styrofoam. Therefore, mass of water displaced is also equal to the following.

             Mass of water displaced = mass of book + mass of Styrofoam

                  1.73 \times 10^{3} g = 1500 g + mass of Styrofoam

                   (1730 - 1500) g = mass of Styrofoam

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Therefore, calculate the density of Styrofoam as follows.

                   Density = \frac{mass}{volume}  

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4 mol (802 kJ/mol) + 2 mol (462 kJ/mol) = 4132.0 kJ

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