Answer: only the VSEPR mode shows the geometric shape of a formula.
Answer:
(a) Hypoeutectic
(b) Alpha solid, aluminium
(c) 70% α
, 30% β
(d) 97.6% α, 2.4% β
(e) 97.6% α, 2.4% β
(f) 97% α, 3% β
Explanation:
(a) The eutectic composition for Al Si alloy is 11.7 wt% silicon, therefore, an Al-4% Si alloy is hypoeutectic
(b) For the hypoeutectic alloy, aluminium, Al, is expected to form first, such that the aluminium content is reduced till the point it gets to the eutectic proportion of 11.7 wt% silicon
(c) At 578°C we have
% α: Al (11 - 4)/(11 - 1) = 70% α
% L: Si 100 - 70 = 30% β
(d) At 576°C we have
α: 99.83% Si (99.83 - 4)/(99.83- 1.65) = 97.6% α
β: 1.65% Si (4 - 1.65)/(99.83- 1.65) = 2.4% β
(e) Primary α: 1.65% α (99.83 - 4)/(99.83 - 1.65) = 97.6% α
Eutectic 4% Si = 100 - 97.6 = 2.4% β
(f) At 25°C we have;
α%: (99.83 - 4)/(99.83 - 1) = 97% α
β%: 100 - 97 = 3% β.
In this reaction 50% of the compound decompose in 10.5 min thus, it is half life of the reaction and denoted by symbol 
.
(a) For first order reaction, rate constant and half life time are related to each other as follows:
Thus, rate constant of the reaction is 
.
(b) Rate equation for first order reaction is as follows:
![k=\frac{2.303}{t_{1/2}}log\frac{[A_{0}]}{[A_{t}]}](https://tex.z-dn.net/?f=k%3D%5Cfrac%7B2.303%7D%7Bt_%7B1%2F2%7D%7Dlog%5Cfrac%7B%5BA_%7B0%7D%5D%7D%7B%5BA_%7Bt%7D%5D%7D)
now, 75% of the compound is decomposed, if initial concentration ![[A_{0} ]](https://tex.z-dn.net/?f=%5BA_%7B0%7D%20%5D)
is 100 then concentration at time t ![[A_{t} ]](https://tex.z-dn.net/?f=%5BA_%7Bt%7D%20%5D)
will be 100-75=25.
Putting the values,
On rearranging,
Thus, time required for 75% decomposition is 21 min.
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