1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
KatRina [158]
3 years ago
14

For the substituted cyclohexane compound given below, highlight the groups – by clicking on atoms – that will sterically interac

t with the methyl group in a 1,3-diaxial fashion.

Chemistry
2 answers:
Usimov [2.4K]3 years ago
8 0

Answer:

            In given structure of substituted cyclohexane select the "Bromine" atom as the answer.

Explanation:

1,3-Diaxial Interactions:

                                     As cleared from name, this type of interactions are found in cyclic alkanes in which one group present at position 1 (assumed number) experiences steric hindrance due to another group present at position 3.

                                  Also, it is necessary that both the groups must be occupying either axial or equatorial positions respectively. For example, in given structure the methyl group at position 1 is at axial position and another bulky group which should interact with this methyl group must occupy axial position at carbon 3 next to carbon 1. Hence, as shown in figure, the Bromine atom is present at third carbon and is at axial position too.

                                    In attached picture, the green lines indicate steric interactions between Methyl group and Bromine atoms which are involved in steric interactions in 1,3-diaxial fashion.

lina2011 [118]3 years ago
4 0

The atoms that would sterically interact with methyl group located axially are highlighted in pink color in the attached image.

Further Explanation:

The stereoisomer of a molecule that has same chemical formula and connectivity of bond but differs in the arrangement of the atoms in space is known as conformer. The rotation about the carbon-carbon single bond can lead to the formation of conformer of a molecule.

There are four conformers of cyclohexane molecule as follows:

  • Chair conformation
  • Boat conformation
  • Twist boat conformation
  • Half chair conformation

Chair conformation is considered as the best conformation of cyclohexane. The hydrogen in blue denote the axial positions and the hydrogen in pink denote equatorial positions. (Refer to the attached image)

The stable conformation is that in which the bulky groups such as hydroxyl, methyl, and nitro group occupy the equatorial positions while the relatively small groups such as hydrogen atoms occupy axial positions. The reason is that the axially placed substituents suffer more steric repulsion and that generates strain in the molecule. The strain leads to high energy and thus less stability.

While writing the chair conformation the bulkier groups are preferentially placed at equatorial positions. The conformation that has bulky group at equatorial position is more favorable than the conformation that has bulky group at axial position. The reason for the stability of the conformation is diaxial interactions.

1,3-diaxial interaction: The 1,3-diaxial interactions occur among the axial substituent present at 1 and 3 positions.

The conformation in the problem has axial substituent hydrogen and bromine at the two positions 3 and 3’ which lead to 1,3-diaxial strain in the molecule and makes it unstable. (Refer to the attached image)

Learn more:

1. Balanced chemical equation brainly.com/question/1405182

2. Oxidation and reduction reaction: brainly.com/question/2973661

Answer details:

Grade: Senior School

Subject: Chemistry

Chapter: Conformation of cyclohexane  

Keywords: Cyclohexane, planar, chair conformation, axial positions, equatorial positions, steric repulsion, high energy, 1, 3-diaxial interaction, 1, 3-diaxial strain.

You might be interested in
How does a foam-filled winter coat help keep a person warm?
Rudik [331]

Answer:

It slows down the transfer of thermal energy from outside to inside the coat.

Explanation:

5 0
3 years ago
how much energy would it take to heat a section of the copper tubing that weights about 660.0 gram, from 12.93 degree Celsius to
expeople1 [14]

Answer:

                      Q  =  2647 J

Explanation:

                    Specific heat capacity is the amount of energy required by one Kg of a substance to raise its temperature by 1 °C.

In thermodynamics the equation used is as follow,

                                                 Q  =  m Cp ΔT

Where;

           Q  =  Heat  =  ?

           m  =  mass  =  660 g

           Cp  =  Specific Heat Capacity  =  0.3850 J.g⁻¹.°C⁻¹

           ΔT  =  Change in Temperature  =  23.35 °C - 12.93 °C  =  10.42 °C

Putting values in eq. 1,

                            Q  =  660 g × 0.3850 J.g⁻¹.°C⁻¹ ×  10.42 °C

                            Q  =  2647 J

8 0
3 years ago
What type of change is the process of solid ice changing into liquid water?
otez555 [7]

The change is called melting

6 0
3 years ago
What does a neutralization reaction produce?
algol13

Answer:

hope this help....

Explanation:

Neutralization is the reaction of an acid and a base, which forms water and a salt. Net ionic equations for neutralization reactions may include solid acids, solid bases, solid salts, and water.

7 0
3 years ago
Read 2 more answers
Rain washing away soil from a hillside
Aneli [31]

Answer:

deposition

Explanation:

8 0
3 years ago
Other questions:
  • What is the mass, in grams, of 1.30×1021 molecules of aspirin, C9H8O4?
    7·2 answers
  • How manhhy neutrons does element x have if its atomic number is 24 and its mass number is 77??
    8·1 answer
  • Which family has the highest ionization energy
    8·1 answer
  • Which of the following compounds contains the tin (IV) ion? A. SnO2 B. SnCl2 C. Sn2O D. Sn4O3
    14·2 answers
  • In which chemical system is molecule to ion attractions present? A) KNO3(s) B) KNO3(l) C) KNO3(aq) D) KNO3(g)
    8·1 answer
  • What does a chemist do​
    9·1 answer
  • The rate constant for the first-order decomposition of n2o is 3.40 s-1. what is the half-life of the decomposition?
    12·2 answers
  • The elementary gas-phase reaction2A → Bis carried out in a constant-volume batch reactor where 50% conversion is achieved in 1 h
    13·1 answer
  • What happens if you don't disconnect the wires in a series circuit?
    5·1 answer
  • How much aluminum oxide are produced when 46.5g of Al react with 165.37g of MnO?
    11·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!