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Ray Of Light [21]
3 years ago
10

A silver cube with an edge length of 2.38 cm and a gold cube with an edge length of 2.79 cm are both heated to 81.9 ∘C and place

d in 109.5 mL of water at 19.6 ∘C . What is the final temperature of the water when thermal equilibrium is reached g
Chemistry
1 answer:
never [62]3 years ago
6 0

Answer:

The final temperature of the water when thermal equilibrium is reached is 23.54 ⁰C

Explanation:

<u>Given data;</u>

edge length of silver, a = 2.38 cm = 0.0238 m

edge length of gold, a = 2.79 cm = 0.0279 m

final temperature of silver, t = 81.9 ° C

final temperature of Gold, t = 81.9 ° C

initial temperature of water, t = 19.6 ° C

volume of water, v =  109.5 mL = 0.0001095 m³

<u>Known data:</u>

density gold 19300 kg/m³

density silver 10490 kg/m³

density water 1000 kg/m³

specific heat gold is 129 J/kgC

specific heat silver is 240 J/kgC

specific heat water is 4200 J/kgC

<u>Calculated data</u>

Apply Pythagoras theorem to determine the side of each cube;

Silver cube;

let L be the side of the silver cube

Taking the cross section of the cube (form a right angled triangle), the edge  length forms the <em>hypotenuse side</em>.

L² + L² = 0.0238²

2L² = 0.0238²

L² = 0.0238² / 2

L² = 0.00028322

L = √0.00028322

L = 0.0168

Volume of cube = L³

Volume of the silver cube = (0.0168)³ = 4.742 x 10⁻⁶ m³

Gold cube;

let L be the side of the gold cube

L² + L² = 0.0279²

2L² = 0.0279²

L² = 0.0279² / 2

L² = 0.0003892

L = √0.0003892

L = 0.0197

Volume of cube = L³

Volume of the silver cube = (0.0197)³ = 7.645 x 10⁻⁶ m³

Mass of silver cube;

density = mass / volume

mass = density x volume

mass of silver cube = 10490 (kg/m³) x 4.742 x 10⁻⁶ (m³) = 0.0497 kg

Mass of Gold cube

mass of gold cube = 19300 (kg/m³) x 7.645 x 10⁻⁶ (m³) = 0.148 kg

Mass of water

mass of water = 1000 (kg/m³) x 0.0001095 (m³) = 0.1095 kg

Let the heat gained by cold water be  Q₁

Let the heat lost  by silver cube = Q₂

Let the heat lost  by gold cube = Q₃

Let the final temperature of water = T

Q₁  = 0.1095 kg x 4200 J/kgC x (T–19.6)

Q₂ = 0.0497 kg x 240 J/kgC x (81.9–T)

Q₃ = 0.148 kg x 129 J/kgC x (81.9–T)

At thermal equilibrium;

Q₁ = Q₂ + Q₃

0.1095 x 4200  (T–19.6)  = 0.0497 x 240 x (81.9–T)  + 0.148 x 129 x (81.9–T)

459.9 (T–19.6) = 11.928 (81.9–T) + 19.092(81.9–T)

459.9T - 9014.04 = 976.9032 - 11.928T + 1563.6348 - 19.092T

459.9T + 11.928T + 19.092T = 9014.04  + 976.9032 + 1563.6348

490.92T = 11554.578

T = 11554.578 / 490.92

T = 23.54 ⁰C

Therefore, the final temperature of the water when thermal equilibrium is reached is 23.54 ⁰C

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To solve this question, we'll begin by writing the balanced equation for the reaction between H₂SO₄ and NaOH. This is illustrated below:

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From the balanced equation above,

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<h3>Volume of the base, NaOH (V_{B}) =? </h3>

\frac{M_{A} * V_{A}}{M_{B} * V_{B}} = \frac{n_{A}}{n_{B}}\\\\\frac{0.505 * 40}{0.505 *V_{B}} = \frac{1}{2}\\\\\frac{20.2}{0.505 *V_{B}} = \frac{1}{2}

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Finally, we shall convert 80 mL to dm³. This can be obtained as follow:

1000 mL = 1 dm^{3}\\\\Therefore,\\\\80 mL = \frac{80 mL * 1dm^{3}}{1000 mL}\\\\80 mL = 0.08dm^{3}

Therefore, the volume of NaOH required is 0.08 dm³

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